XPS study of metal complexes with an unsymmetrical tridentate Schiff base

Thermal and spectroscopic (IR, XPS) properties of lanthanide(III) benzene-1,3,5-triacetate complexes

“…-3d 5/2 ) is 16.7, 3.3 and 3.2 eV, respectively. Satellites are assigned to charge-transfer shake-up from ligand to empty 4f orbital [38][39][40][41]. One peak corresponds to the final state without the charge transfer 4f 0 , and the satellite peak corresponds to the final state after transfer of electron (4f 1 ) from ligand to 4f orbital of Ln(III).…”

Hexagonal La2O3 Nanocrystals Chemically Coupled with Nitrogen‐Doped Porous Carbon as Efficient Catalysts for the Oxygen Reduction Reaction

“…As illustrated in Ta ble 2, the content of Os peciesi n La 2 O 3 /NPC is 13.72 %( atomic percentage), which is reduced to 9.52 %( atomicp ercentage) after subtractingt he content of O atoms in the supported La 2 O 3 .T here is ar emarkable decrease .0 AE 0.2eV), and oxid-N (oxidizedN ,4 02.0 AE 0.2 eV) in the samples,. [15] The atomic content of the five structural nitrogen atoms are given in Figure 2D.D ifferent from the NPC sample, after loading lanthanum oxide, the content of oxidized Ni n La 2 O 3 /NPC increased significantly to 0.88 %( referring to N/C unless other stated),w hereas the level of graphitic Nd ecreased. The reason mayb et hat the graphitization of the carbon layer is damaged to some extent during the oxide deposition process.…”

Boosting Highly Ordered Porosity in Lanthanum Metal-Organic Frameworks for Ring-Opening Polymerization of γ-Butyrolactone

“…Taking NNU-mIM-3, for example, a new weak peak of NNU-mIM-3 appears at 856.6 eV compared with that of La-BTB, which might be ascribed to the peak position of La-N at 856.4 eV (Figure S9B). 37 This indicates that the addition of 1-mIM might substitute the solvent molecule like water. Further, proven by the elemental and inductive coupled plasma emission spectrometer (ICP) analyses, the formula of NNU-mIM-3 is calculated to be La(BTB) 0.63 (DMF) 0.19 (1-mIM) 0.13 (H 2 O) 0.8 .…”