2024
DOI: 10.3390/molecules29091963
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Y(OTf)3-Salazin-Catalyzed Asymmetric Aldol Condensation

Chengzhuo Wang,
Ning Chen,
Zhanhui Yang
et al.

Abstract: The chiral aziridine-containing vicinal iminophenol tridentate ligands (named salazins) are a class of readily prepared chiral ligands from enantiopure aziridines and salicylaldehydes. Their scandium and yttrium triflate complexes show excellent reactivity and enantioselectivities in the catalytic asymmetric aldol condensation of electron-deficient aromatic aldehydes and ketones, including acetone and cycloalkanones. The stereoselectivity is rationalized to the strong π–stacking interaction between aromatic al… Show more

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