The visually brightest stars in globular clusters (GCs) are the ones evolving off the asymptotic giant branch (AGB) and passing through spectral types F and A-the "yellow" post-AGB (yPAGB) stars. yPAGB stars are potentially excellent "Population II" standard candles for measuring extragalactic distances. A recent survey of the Galactic GC system, using uBVI photometry to identify stars of low surface gravities with large Balmer discontinuities, discovered a candidate luminous yPAGB star in the GC M19 (NGC 6273), designated ZNG 4. The same survey also identified a bright, hotter candidate blue PAGB star, ZNG 2, lying near the top of the white-dwarf cooling sequence. Both PAGB candidates have proper motions and parallaxes in the recent Gaia Early Data Release 3 consistent with cluster membership, but they still lacked spectroscopic verification. Here we present moderateresolution spectra of both stars, confirming them as low-gravity objects that are extremely likely to be cluster members. Through comparison with a library of synthetic spectra, we made approximate estimates of the stars' atmospheric parameters. We find that the yPAGB star ZNG 4 has an effective temperature of T eff 6500 K, a surface gravity of log g 1, and a metallicity of [Fe/H] −1.5, similar to that of the host cluster. The blue PAGB star ZNG 2 has T eff 18000 K, log g 3, and an apparently low metallicity in the range of [Fe/H] −2.0 to −2.5. Both stars are bright (V = 12.5 and 13.3, respectively). We urge high-dispersion spectroscopic follow-up to determine detailed atmospheric parameters and chemical compositions, and to monitor radial velocities.