Despite the evident advantages of combining masonry with prestress, their joint use has been poorly exploited during the last decades. This paper claims the high potential of masonry as a primary load-bearing material when combined with post-tensioning. This work deals with arch footbridges and antifunicular structures. With respect to the first, this research illustrates the introduction of external loads by internal post-tensioning to favourably increase the axial forces in a masonry arch, and consequently improving its structural behaviour. With respect to the second, this work shows how bending moments in a non-funicular 2D curved geometry can be eliminated through an external post-tensioning system. In summary, this research strongly expands the range of post-tensioned masonry structures that exhibit a bending-free (or quasi bending-free) behaviour and, de facto, opens up new possibilities for designs that combine structural efficient solutions with traditional materials.