The values of relative cumulative yields of 12 products (85mKr, 91mY, 92Sr, 97Zr, 99Mo, 105Ru, 133I, 134I, 135I, 138Cs, 139Ba, 142La, 143Ce) of the 239Pu photofission was measured at a maximum bremsstrahlung energy of 17.5 MeV (av-erage excitation energy ~ 12.03 MeV). 239Pu photofission reaction was stimulated on the electron accelerator of the Institute of Electron Physics NAS of Ukraine – M-30 microtron to simulate the spectra of bremsstrahlung’s photons, secondary electrons, and photoneutrons that hit the 239Pu target, the GEANT4 code was used. The input of accom-panying nuclear reactions to the yield of 239Pu photofission products for the given experimental parameters was also evaluating. The obtained experimental data of the yields of products 239Pu photofission were compared with the program codes GEF and Talys1.9.5 simulations.