The yrast level structure of 216 Rn has been studied using in-beam spectroscopy α-γ -γ coincidence techniques through the 208 Pb( 18 O, 2α2n) reaction in the 91-93 MeV energy range, using the 8π GASP-ISIS spectrometer at Legnaro. The level scheme of 216 Rn resulting from this study shows alternating parity bands only above a certain excitation energy. From this result, the lightest nucleus showing evidence of octupole collectivity at low spins is still 216 Fr, thereby defining the lowest-mass corner for this kind of phenomenon as N 129 and Z 87.