Yttrium containing head-on complexes of silico- and germanotungstate: Synthesis, structure and solution properties

Hussain, Firasat; Degonda, A.; Sandriesser, Stefan; Fox, Thomas; Mal, Sib Sankar; Kortz, Ulrich; Patzke, Greta R.

doi:10.1016/j.ica.2010.07.053

Cited by 19 publications

(10 citation statements)

References 35 publications

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“…The Y–Y distance of 3.42 Å is too short to allow an oxide ion to occupy the central cavity, in contrast to the cavities of 1 , 3 a , and 5 . The distances and angles of the 2 previous structurally characterized Rb and Y species,, general metal alkoxide structures of Rb− and Y and other analogous literature structures were found to be within the observed values ,,…”

Section: Resultssupporting

confidence: 70%

Alkali Metal Yttrium neo‐Pentoxide Double Alkoxide Precursors to Alkali Metal Yttrium Oxide Nanomaterials

et al. 2016

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A series of alkali metal yttrium neo-pentoxide ([AY(ONep) 4 ]) compounds were developed as precursors to alkali yttrium oxide (AYO 2 ) nanomaterials. The reaction of yttrium amide ([Y (NR 2 ) 3 ] where R = Si(CH 3 ) 3 ) with four equivalents of H-ONep followed by addition of [A(NR 2 )] (A = Li, Na, K) or A o (A o = Rb, Cs) led to the formation of a complex series of A n Y(ONep) 3 + n species, crystallographically identified as [Y 2 Li 3 (m 3 -ONep)(m 3 -HONep)(m-ONep) 5 (ONep) 3 (HONep) 2 ](1), [YNa 2 (m 3 -ONep) 4 (ONep)] 2 (2), (5). Compounds 1-5 were investigated as single source precursors to AYO x nanomaterials following solvothermal routes (pyridine, 185 o C for 24 h). The final products after thermal processing were found by powder X-ray diffraction experiments to be Y 2 O 3 with variable sized particles based on transmission electron diffraction. Energy dispersive Xray spectroscopy studies indicated that the heavier alkali metal species were present in the isolated nanomaterials.[a] Dr.

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Section: Resultssupporting

confidence: 70%

Alkali Metal Yttrium neo‐Pentoxide Double Alkoxide Precursors to Alkali Metal Yttrium Oxide Nanomaterials

et al. 2016

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“…This hetero Keggin anion is found to be the mixture of isomers {( 1,2 ), ( 1,4 ), ( 1,5 ), ( 1,6 ) and ( 1,11 )} . It is not stable in aqueous solution which further leads to the formation of tetra‐metallic species [M 4 (OH 2 ) 2 (PW 9 O 34 ) 2 ] . This reaction was carried out in the presence of Y III ion, resulting in the formation of sandwiched complex.…”

Section: Resultsmentioning

confidence: 99%

“…Later in 2010, Hussain et al. reported the synthesis, crystal structure and solution properties of two dimeric yttrium containing head‐on complexes of tungstosilicates and tungstogermanates . In 2011, Kortz group have reported the synthesis of yttrium (III)‐containing tungsto‐antimonate (III).…”

Section: Introductionmentioning

confidence: 99%

Syntheses, and Crystal Structures of Y^III Containing Di‐Metal Substituted 1,5 Isomers of Heterometallic Tungstophosphate Nanoclusters: [Y{PM₂W₁₀O₃₈(H₂O)₂}₂]^11– (M=Co^II and Zn^II)

et al. 2019

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Two new YIII containing sandwich‐type heterometallic tungstophosphates: [Y{PM2W10O38(H2O)2}2]11– (M = CoII (1) and ZnII (2)) have been synthesized under mild reaction conditions. Both the molecular complexes 1 a and 2 a were synthesized by reacting Y(NO3)3⋅6H2O, M(NO3)2⋅6H2O (M = CoII and ZnII) with Wells‐Dawson type divacant K14[P2W19O69(H2O)]⋅24H2O precursor. The potassium salts of single crystalline material were collected and further used for characterization with different analytical techniques including single crystal X‐ray diffraction (SC‐XRD), Fourier transform infrared (FT‐IR) spectroscopy, inductively coupled plasma atomic emission spectroscopy (ICP‐AES), 31P, 183W and 89Y nuclear magnetic resonance (NMR) spectroscopy, high‐resolution electro‐spray ionization mass spectrometry (HR‐ESI‐MS) as well as thermogravimetric analysis. Single crystal X‐ray diffraction analysis shows that both polyanions crystallize in the orthorhombic crystal system with space group Iba2. Each polyanion consists of (1,5) isomer of di‐metal substituted α‐Keggin type tungstophosphates, which sandwiched a YIII ion.

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“…In the dimeric structures of {RE(α-XW 11 O 39 )(H 2 O)} 2 [X = Si, Ge, P], acetic acid units act as linkers via (η 2 , μ -1,1) fashion, connecting two RE centers. The atomic radius of metals has an important role in the construction of such compounds ( Table 2 ) [ 116 , 117 , 118 , 119 ]. When Na 9 [ B - α -AsW 9 O 33 ] as precursor reacts to RE ions, it is involved in decomposition and rearrangement reactions that leads to the formation of [B- b -AsW 9 O 33 ] −9 , {W 3 O 13 }, {W 2 O 10 }, and {WO 6 } fragments.…”

Section: Inorganic–organic Hybrids Based On Respsmentioning

confidence: 99%

Roles of Organic Fragments in Redirecting Crystal/Molecular Structures of Inorganic–Organic Hybrids Based on Lacunary Keggin-Type Polyoxometalates

Khajavian¹,

Jodaian²,

Taghipour³

et al. 2021

Molecules

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Lacunary polyoxometalates (LPOMs) are key precursors for the synthesis of functional POMs. To date, reviews dedicated to behavioral studies of LPOMs often comprise the role of metal ions, including transition metal (TM) and rare earth (RE) ions, in extending and stability of high-nuclearity clusters. In contrast, the role of organic ligands in the structures and properties of lacunary-based hybrids has remained less explored. In this review, we focus on the role of organic fragments in the self-assembling process of POM-based architectures and discuss relationships between the nature and structure of organic ligand and properties such as the topology of hybrid inorganic–organic material in RE and TM-RE heterometallic derivatives of lacunary Keggin-type POMs. The effects of organic fragment in mixed ligand hybrids are also briefly reviewed.

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Yttrium containing head-on complexes of silico- and germanotungstate: Synthesis, structure and solution properties

Cited by 19 publications

References 35 publications

Alkali Metal Yttrium neo‐Pentoxide Double Alkoxide Precursors to Alkali Metal Yttrium Oxide Nanomaterials

Alkali Metal Yttrium neo‐Pentoxide Double Alkoxide Precursors to Alkali Metal Yttrium Oxide Nanomaterials

Syntheses, and Crystal Structures of Y^III Containing Di‐Metal Substituted 1,5 Isomers of Heterometallic Tungstophosphate Nanoclusters: [Y{PM₂W₁₀O₃₈(H₂O)₂}₂]^11– (M=Co^II and Zn^II)

Roles of Organic Fragments in Redirecting Crystal/Molecular Structures of Inorganic–Organic Hybrids Based on Lacunary Keggin-Type Polyoxometalates

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Yttrium containing head-on complexes of silico- and germanotungstate: Synthesis, structure and solution properties

Cited by 19 publications

References 35 publications

Alkali Metal Yttrium neo‐Pentoxide Double Alkoxide Precursors to Alkali Metal Yttrium Oxide Nanomaterials

Alkali Metal Yttrium neo‐Pentoxide Double Alkoxide Precursors to Alkali Metal Yttrium Oxide Nanomaterials

Syntheses, and Crystal Structures of YIII Containing Di‐Metal Substituted 1,5 Isomers of Heterometallic Tungstophosphate Nanoclusters: [Y{PM2W10O38(H2O)2}2]11– (M=CoII and ZnII)

Roles of Organic Fragments in Redirecting Crystal/Molecular Structures of Inorganic–Organic Hybrids Based on Lacunary Keggin-Type Polyoxometalates

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Syntheses, and Crystal Structures of Y^III Containing Di‐Metal Substituted 1,5 Isomers of Heterometallic Tungstophosphate Nanoclusters: [Y{PM₂W₁₀O₃₈(H₂O)₂}₂]^11– (M=Co^II and Zn^II)