Zen law and features of liquidus-solidus curves in binary state diagrams based on elements VIIIA and IB of the periodic table

Потекаев, А. И.; Kondratyuk, A. A.; Porobova, S A; Клопотов, А. А.; Markova, T. N.; Kakushkin, Yu A; Klopotov, Vladimir D.

doi:10.1088/1757-899x/156/1/012030

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2021

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“…Potekaev et al [9,10] established the explicit correlation between the type of evolution of the binary phase diagrams based on elements of VIIIA and IB groups of Mendeleyev's Periodic Table and the nature (positive/negative) of the superstructure contraction.…”

Section: Introductionmentioning

confidence: 99%

Analytic Binary Alloy Volume–Concentration Relations and the Deviation from Zen’s Law

et al. 2021

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Alloys expand or contract as concentrations change, and the resulting relationship between atomic volume and alloy content is an important property of the solid. While a well-known approximation posits that the atomic volume varies linearly with concentration (Zen’s law), the actual variation is more complicated. Here we use the apparent size of the solute (solvent) atom and the elasticity to derive explicit analytical expressions for the atomic volume of binary solid alloys. Two approximations, continuum and terminal, are proposed. Deviations from Zen’s law are studied for 22 binary alloy systems.

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Section: Introductionmentioning

confidence: 99%