2023
DOI: 10.1002/adfm.202312941
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ZIF‐67‐Derived Antivirus Cobalt Hydroxide LDH Nanosheets Produced through High‐Concentration Cobalt Ion‐Assisted Hydration

Ben Wu,
Guofang Zhang,
Jiawen Ji
et al.

Abstract: In this study, a novel strategy is developed for the first time, referred to as high‐concentration cobalt ion‐assisted hydration (HCCAH) utilizing zeolitic imidazolate framework‐67 (ZIF‐67) as a precursor, to produce independent and flat α‐cobalt hydroxide nanosheets (CHN). These nanosheets offer abundant contact sites for binding with virus surface proteins. The formation of CHN involves the in situ transformation from ZIF‐67, due to the matching of the hydrolysis rate of ZIF‐67 and in situ growth rate of cob… Show more

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“…ZIF is susceptible to hydrolysis in water. Even a trace amount of metal ions, H + , or OH – catalyzes the process. On the other hand, PBAs are stable in neutral and slightly acidic solutions but not in an alkaline medium. Therefore, the mechanism of the hydrothermal phase transition of ZIF is not exactly the same as that of PBA, and we will discuss it only qualitatively. Hydrothermal derivatives of CoFe-ZIF materials were prepared by adjusting the pH of water.…”
Section: Resultsmentioning
confidence: 99%
“…ZIF is susceptible to hydrolysis in water. Even a trace amount of metal ions, H + , or OH – catalyzes the process. On the other hand, PBAs are stable in neutral and slightly acidic solutions but not in an alkaline medium. Therefore, the mechanism of the hydrothermal phase transition of ZIF is not exactly the same as that of PBA, and we will discuss it only qualitatively. Hydrothermal derivatives of CoFe-ZIF materials were prepared by adjusting the pH of water.…”
Section: Resultsmentioning
confidence: 99%