The chromium isotope compositions of 27 metamorphic mafic rocks with varying metamorphic degrees from eastern China were systematically measured to investigate the Cr isotope behavior during continental crust subduction. The Cr isotope compositions of all samples studied were Bulk Silicate Earth (BSE) like, with d 53 Cr NIST979 of greenschists, amphibolites, and eclogites ranging from 20.06& to 20.17&, 20.05& to 20.27&, and 20.01& to 20.24&, respectively. The lack of resolvable isotopic variability among the metamorphic rocks from different metamorphic zones indicated that no systematic Cr isotope fractionation was associated with the degree of metamorphism. However, the Cr isotopic variability among homologous samples may have reflected effects induced by metamorphic dehydration with a change of redox state, rather than protolith heterogeneity (i.e., magma differentiation). In addition, the differences in d 53 Cr (D 53 Cr Cpx-Gt ) between coexisting clinopyroxene (Cpx) and garnet (Gt) from two garnet pyroxenites were 0.06& and 0.34&, respectively, indicating that significant inter-mineral Cr isotope disequilibria could occur during metamorphism. To provide a basis for comparison with metamorphic rocks and to provide further constraints on the potential Cr isotope heterogeneity in the mantle and in the protolith of some metamorphic rocks, we analyzed mantle-derived chromites and the associated peridotites from Luobusa, and we obtained the following general order: chromite-free peridotites (20.21& to 20.11&) < chromite-bearing peridotite (20.07&) < chromite (20.06&). These findings imply potential mantle heterogeneity as a result of partial melting or fractional crystallization associated with chromite.
Key Points:It is the first time to investigate Cr isotopic behaviors during subduction We obtain the limited Cr isotopic fractionation during metamorphic dehydration There are potential Cr isotopic fractionations between hightemperature minerals (2015), Chromium isotope signature during continental crust subduction recorded in metamorphic rocks, Geochem.
PUBLICATIONSDue to the high compatibility of chromium during magma activity, ultramafic and mafic rocks are the major reservoirs of Cr in Bulk Silicate Earth (BSE) [Faure, 1991]. Schoenberg et al. [2008] first studied the Cr isotope compositions of a variety of mantle-derived rocks, including mantle xenoliths, ultramafic rocks, cumulates, and oceanic and continental basalts. The Cr isotope composition (d 53 Cr NIST979 ) of the investigated samples was in a limited range of 20.21& to 20.02& with an average value of 20.12 6 0.10& (2SD), implying that mantle-derived rocks have relatively homogenous Cr isotope compositions. Farka s et al. [2013] observed that the global igneous chromites have slightly heavier Cr isotope compositions with an average d 53 Cr NIST 979 value of 20.08 6 0.13& (2SD) compared with the BSE reported by Schoenberg et al. [2008] and then inferred that chromite-bearing mantle might be isotopically heavier than mantle without chromites. This phe...