At a severe accident of nuclear power plants with light-water reactors, the most effective way to localize the forming melt (corium) is to keep it in the cooled reactor vessel, the integrity of which depends on the value of heat flux from the melt to the reactor vessel. In this case, one of the critical processes is the melt oxidation by a water steam or a steam-air mixture. It process can lead to a significant increase in the thermal load on the reactor vessel due to a heat of exothermic reactions of oxidation of reducing agents, which presents in the melt, a thickness decreasing of the metallic part of the molten pool, and a hydrogen release. All of these factors strictly depends on the rate of oxidation. When considering the conditions of melt oxidation, it taken into account that for the accepted scenarios of a severe accident, the most realistic situation is the presence of a solid-phase oxide layer (oxidic crust) on the melt surface. Under these conditions, a dependence for calculating the rate of core melt oxidation based on the diffusion model proposed and its validation by using the obtained experimental data performed.