Zn2SnO4 particles coated with N-doped carbon as an anode material for lithium and sodium-ion batteries

Kim, Nam‐Young; Shim, Jae-Hyun; Jae, Woojin; Song, Jungwook; Kim, Jongsik

doi:10.1016/j.jallcom.2019.01.370

Cited by 27 publications

(12 citation statements)

References 61 publications

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“…3b). Two major peaks at 487.4 and 495.8 eV are attributed to Sn 4+ 3d 5/2 and Sn 4+ 3d 3/2 in SnO 2 /Zn 2 SnO 4 , 38,48 respectively. For the Zn 2p high-resolution XPS spectra (Fig.…”

Section: Resultsmentioning

confidence: 97%

“…Kim et al reported Co 3 Sn 2 and SnO 2 core-shell heterostructures (Co 3 Sn 2 @SnO 2 CSHs) as an anode material that delivers a high reversible capacity and an outstanding energy density for lithium dual-ion batteries due to its unique microstructure. 19 Inverse spinel structured Zn 2 SnO 4 is a type of Sn-based oxide anode for LIBs, [36][37][38] and has similar low operating potentials to ZnO and SnO 2 , and low toxicity. 39 However, the Zn 2 SnO 4 -based heterostructures have not been reported.…”

Section: Introductionmentioning

confidence: 99%

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Design and synthesis of a 3D graphene-enhanced electrode for fast charge/ion transport for lithium storage

et al. 2022

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“…3b). Two major peaks at 487.4 and 495.8 eV are attributed to Sn 4+ 3d 5/2 and Sn 4+ 3d 3/2 in SnO 2 /Zn 2 SnO 4 , 38,48 respectively. For the Zn 2p high-resolution XPS spectra (Fig.…”

Section: Resultsmentioning

confidence: 97%

Section: Introductionmentioning

confidence: 99%

Design and synthesis of a 3D graphene-enhanced electrode for fast charge/ion transport for lithium storage

et al. 2022

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“…Subsequently, a rapid decline in mass is observed from 400 °C to 550 °C. This part of the mass loss is assigned to the production of SeO2 and pyrolysis and oxidation behavior of carbon material 45 , and finally, In2O3 is obtained at 750 °C. Through calculation, the proportion of carbon in In2Se3@C and its rGO-modified composites is 27.9%, and 38.2% respectively.…”

Section: Resultsmentioning

confidence: 99%

RGO-Coated MOF-Derived In<sub>2</sub>Se<sub>3</sub> as a High-Performance Anode for Sodium-Ion Batteries

Lv¹,

Wang²,

Yu³

et al. 2022

Acta Physico Chimica Sinica

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MOF-derived metal selenides are promising candidates as effective anode materials in sodium-ion batteries (SIBs) owing to their ordered carbon skeleton structure and the high conductivity of selenides. They can be imparted with rapid electron/ion transport channels for the insertion/de-insertion of Na + . In this study, MOFderived In2Se3 was prepared as an anode material for SIBs. However, the large volume expansion during cycling leads to structural collapse, which affects the charging and discharging circulation life of the battery. To address this, a two-dimensional rGO network was introduced on the MOF-derived In2Se3 surface by surface modification. Field-emission scanning electron microscopy (FE-SEM) and X-ray photoelectron spectroscopy (XPS) results confirmed the successful synthesis of the In2Se3@C/rGO composite. The structures with two types of carbon enhanced the charge transfer kinetics and provided two stress-buffering layers. Thus, the volume change could be accommodated and simultaneously, electron transfer was accelerated. This technique was effective, as proved by the enhanced capacity retention of 95.2% at 1 A•g −1 after 500 cycles. In contrast, the capacity retention of the MOF-derived material without rGO was only 74.2%. Additionally, due to the synergistic effect of the rGO network and the MOF-derived In2Se3, the anode showed a superior capacity of 468 mAh•g −1 at 0.1 A•g −1 . Conversely, at the same current density, the uncoated material delivered only a capacity of 393 mAh•g −1 . To study the electrochemical process of the electrode, the In2Se3@C/rGO electrode was subjected to cyclic voltammetry (CV) measurements; the results showed that the In2Se3@C/rGO electrode had notable electrochemical reactivity. In addition, in situ X-ray diffraction (XRD) was performed to explore the sodium storage mechanism of In2Se3, demonstrating that In2Se3 had a dual Na + storage mechanism involving conversion and alloying reactions, and revealing the origin of its high theoretical specific capacity. This study is expected to serve as a reference for preparing optimized rGO-based materials for use as SIB anodes.

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“…The most researched materials for Na-ion battery cathodes are layered structured oxides (NaMO 2 , where M = Co, Ni, Fe, Ti, Cr or a mixture of two or more transition metals) [44][45][46][47][48][49]. This is mainly attributed to current Li-ion batteries also using these types of cathodes.…”

Section: Metal Oxides As Cathodes In Na-ion Batteriesmentioning

confidence: 99%

Beyond Lithium-Based Batteries

et al. 2020

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We discuss the latest developments in alternative battery systems based on sodium, magnesium, zinc and aluminum. In each case, we categorize the individual metals by the overarching cathode material type, focusing on the energy storage mechanism. Specifically, sodium-ion batteries are the closest in technology and chemistry to today’s lithium-ion batteries. This lowers the technology transition barrier in the short term, but their low specific capacity creates a long-term problem. The lower reactivity of magnesium makes pure Mg metal anodes much safer than alkali ones. However, these are still reactive enough to be deactivated over time. Alloying magnesium with different metals can solve this problem. Combining this with different cathodes gives good specific capacities, but with a lower voltage (<1.3 V, compared with 3.8 V for Li-ion batteries). Zinc has the lowest theoretical specific capacity, but zinc metal anodes are so stable that they can be used without alterations. This results in comparable capacities to the other materials and can be immediately used in systems where weight is not a problem. Theoretically, aluminum is the most promising alternative, with its high specific capacity thanks to its three-electron redox reaction. However, the trade-off between stability and specific capacity is a problem. After analyzing each option separately, we compare them all via a political, economic, socio-cultural and technological (PEST) analysis. The review concludes with recommendations for future applications in the mobile and stationary power sectors.

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Zn2SnO4 particles coated with N-doped carbon as an anode material for lithium and sodium-ion batteries

Cited by 27 publications

References 61 publications

Design and synthesis of a 3D graphene-enhanced electrode for fast charge/ion transport for lithium storage

Design and synthesis of a 3D graphene-enhanced electrode for fast charge/ion transport for lithium storage

RGO-Coated MOF-Derived In<sub>2</sub>Se<sub>3</sub> as a High-Performance Anode for Sodium-Ion Batteries

Beyond Lithium-Based Batteries

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