“…To overcome this challenge, scientists worldwide are making tremendous attempts to design novel and desirable electrode materials that can meet a massive energy density. The development of novel battery-type electrodes with excellent structural properties has been an efficient strategy to boost the energy density of SCs with no sacrifice of power density. − Moreover, it has been proved that the intrinsic and geometrical properties of electrode materials are the key aspects which affect the electrochemical performances of SCs. − It is believed that binary transition metal oxides such as NiCo 2 O 4 , FeCo 2 O 4 , CuCo 2 O 4 , and ZnCo 2 O 4 are the promising battery-type electrodes for SCs because of their environmental stabilities and the synergetic effects of different active metal ions providing high electrochemical performances. − Among different types of binary metal oxides, spinel copper cobaltite (CuCo 2 O 4 ) has gained more attention thanks to its inherent advantages such as the environmental friendliness of the copper element, low cost, and multiple oxidation states which result in high theoretical capacity, higher electrochemical activity, and better electrical conductivity compared to other binary metal oxides and single counterparts such as CuO and Co 3 O 4 . So far, various synthetic routes such as hydrothermal, microwave, chemical precipitation sol–gel, and so on have been developed to synthesize pure CuCo 2 O 4 or its composite with different morphologies for SCs.…”