“…Considering that the equipment requirement is relatively high for the former method, most researchers used the latter one. Minor alloying has been proved to be a simple and effective way to develop large-size BMGs, such as Pd- [9,10], Fe- [11], Co- [12], Ni- [13], Mg- [14], Cu- [15], and Zr-based [16] BMGs. Among them, Zr-based BMGs have attracted increasing attention due to their high glass-forming ability and wide supercooled liquid region.…”