“…Excess Gibbs energies in the ternary liquid and solid phases were calculated from the values for the three binary systems by means of the "Kobler interpolation equations" (27) G E = (1 -X Pu ) 2 Gg /Zr + (1 -Xu) 2 Gf r/Pu + (l -X Zr ) 2 G u/Pu [10] in which G E at a ternary composition point is calculated from the values G|j, Zr results should be discounted. Nevertheless, the general shape of the reported isotherms is the same as that of the calculated isotherms.…”
Section: Calculation Of the Ternary Phase Diagrammentioning
Renewed interest in metallic fuel for nuclear reactors has prompted study of the solidus and liquidus for the uranium-plutonium-zirconium system. These temperatures are of importance in assessing the possibility of fuel melting during abnormal reactor conditions. Data obtained in previous work in this area were found to be inadequate for the needs of the current reactor development effort. A dual effort was undertaken to provide the needed data. These were (1) thermodynamic phase diagram analysis and calculation of the ternary solidus and liquidus surfaces and (2) experimental determination of solidus and liquidus temperatures for selected alloys. The methods used and results obtained are described.
“…Excess Gibbs energies in the ternary liquid and solid phases were calculated from the values for the three binary systems by means of the "Kobler interpolation equations" (27) G E = (1 -X Pu ) 2 Gg /Zr + (1 -Xu) 2 Gf r/Pu + (l -X Zr ) 2 G u/Pu [10] in which G E at a ternary composition point is calculated from the values G|j, Zr results should be discounted. Nevertheless, the general shape of the reported isotherms is the same as that of the calculated isotherms.…”
Section: Calculation Of the Ternary Phase Diagrammentioning
Renewed interest in metallic fuel for nuclear reactors has prompted study of the solidus and liquidus for the uranium-plutonium-zirconium system. These temperatures are of importance in assessing the possibility of fuel melting during abnormal reactor conditions. Data obtained in previous work in this area were found to be inadequate for the needs of the current reactor development effort. A dual effort was undertaken to provide the needed data. These were (1) thermodynamic phase diagram analysis and calculation of the ternary solidus and liquidus surfaces and (2) experimental determination of solidus and liquidus temperatures for selected alloys. The methods used and results obtained are described.
“…In this paper, the thermodynamic properties for the ternary Cu-In-Sn system are calculated for the sections with constant molar ratio In:Cu=1:1, 1:4, 4:1 and 9:1 at 873K up to 1673 K and by different models Kohler [10] [11].…”
Section: Resultsmentioning
confidence: 99%
“…There are usually two kinds of models which are popular for description of ternary systems. These are geometrical models symmetric [10] and asymmetric [11] models.…”
“…In the case of non-ideal mixture, molar volume can be expressed by the relation: (13) where: The excess of molar volume mixture can be described in a way analogous to the excess molar free energy of ternary solution with use of models [10][11][12][13][14][15][16]. If ternary and all three binary solutions, which can be formed with ternary mixture components were regular, Toop's model [10] would describe its thermodynamic properties rigorously.…”
Section: Modeling Of Density Of Ternary Mixturesmentioning
Density of the copper-rich corner of the ternary Cu-Pb-Fe alloys was determined with the dilatometric method. Investigated alloys had constant copper content equal to 0.9, 0.8 and 0.7 mole fraction, and varied iron concentration up to 0.1 mole fraction. A model predicting the density of ternary solution from knowledge of density of pure component and the excess of molar volume for limiting binaries is proposed.
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