β-chlorovinylaldehydes as intermediates in the synthesis of new substituted β–fluoroalkoxyvinyl aldehydes and corresponding alcohols

Ghrairi, Sondes; Essalah, Khaled; Crousse, Benoı̂t; Barhoumi‐Slimi, Thouraya

doi:10.1016/j.jfluchem.2021.109837

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Crystallographic Data Collection Structure Determination And...1

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Cited by 4 publications

(2 citation statements)

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“…Crystal data, data collection and structure refinement details are summarized in Table 8. CCDC 2084634 (24) -2084224 (36) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.…”

Section: Crystallographic Data Collection Structure Determination And...mentioning

confidence: 99%

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A one-pot synthesis and X-Ray structural characterization of new highly substituted-allyl carbamates

Ghrairi

Retailleau

Crousse

et al. 2022

Journal of Molecular Structure

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Section: Crystallographic Data Collection Structure Determination And...mentioning

confidence: 99%

“…In our previous works, we have explored the reactivity of the β-chlorovinyl aldehydes as precursors of highly substituted β-fluoroalkoxyvinyl aldehydes and corresponding alcohols [36], benzenes [37], allylic alcohols [38],…”

Section: Introductionmentioning

confidence: 99%

A one-pot synthesis and X-Ray structural characterization of new highly substituted-allyl carbamates

Ghrairi

Retailleau

Crousse

et al. 2022

Journal of Molecular Structure

Self Cite

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β‐halovinyl Aldehydes: Multifaceted Versatile Building Blocks In Organic Synthesis

Saini,

Jyoti,

Sharma

et al. 2024

Eur J Org Chem

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β‐halovinyl aldehydes serve as a valuable building blocks in organic synthesis. These aldo‐x bifunctional building blocks (AXB3s) contain a alkenic double bond (vinyl) as well as a formyl group along with a halogen atom (Cl, Br, I) bonded with the β‐carbon atom of vinyl aldehyde. Owing to the presence of these multiple reactive sites, β‐halovinyl aldehydes act as a suitable precursor for Michael addition, direct addition, cross‐coupling reactions, condensation reactions, nucleophilic substitution reactions, domino reactions, MCRs, Diels‐Alder reaction, functional group transformation reactions and enantioslective transformations. Therefore, a comprehensive review on synthetic exploration of β‐halovinyl aldehydes has been carried out for the generation of reactive intermediates and diverse bioactives heterocycles by using various C‐C, C‐N, C‐S and C‐O bond forming reactions. In this review, we have assembled the literature from mid‐2007 to Jan 2024.

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Chemoselective chlorination of 1,5-benzodiazepin-2-one derivatives by activated DMSO

Ghabi,

Mtiraoui,

Haouas

et al. 2023

Journal of Molecular Structure

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β-chlorovinylaldehydes as intermediates in the synthesis of new substituted β–fluoroalkoxyvinyl aldehydes and corresponding alcohols

Cited by 4 publications

References 44 publications

A one-pot synthesis and X-Ray structural characterization of new highly substituted-allyl carbamates

A one-pot synthesis and X-Ray structural characterization of new highly substituted-allyl carbamates

β‐halovinyl Aldehydes: Multifaceted Versatile Building Blocks In Organic Synthesis

Chemoselective chlorination of 1,5-benzodiazepin-2-one derivatives by activated DMSO

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