β-delayed proton emission from nuclides in the neighborhood of 100 Sn was studied at the National Superconducting Cyclotron Laboratory. The nuclei were produced by fragmentation of a 120 MeV/nucleon 112 Sn primary beam on a Be target. Beam purification was provided by the A1900 Fragment Separator and the Radio Frequency Fragment Separator. The fragments of interest were identified and their decay was studied with the NSCL Beta Counting System (BCS) in conjunction with the Segmented Germanium Array (SeGA +1.9 −1.7 %, 1.3(5)%, 1.9(1)%, 7.5(5)% and 2.5(3)%, respectively. The b βp = 22(1)% for 101 Sn was deduced with higher precision than previously reported. The impact of the newly measured b βp values on the composition of the type-I X-ray burst ashes was studied.