γ-Aminobutyrohydroxamate resins as stationary phases of chelation ion chromatography

Novel ion chromatographic stationary phases for the analysis of complex matrices

“…The incorporation of short chelating columns within a modified IC system, for on-line analyte preconcentration and removal from complex matrices, prior to separation using ion exchange, is the basis of the Dionex chelation ion chromatography (CIC) system. This system has been successfully applied to the analysis of many complex samples over the past 14 years since its inception, [72][73][74][75][76][77][78][79][80][81][82][83][84] including trace metals in seawater, [72][73][74]77,83 geological digests, 76,[78][79][80] biological samples, 72,80,82,84 drinking water, 81 fertilizers 79 and reagent grade chemicals. 82 However, here we will briefly focus on the application of chelating stationary phases for the direct analysis of complex sample matrices, so-called high-performance chelation ion chromatography (HPCIC), as last reviewed by Jones and Nesterenko in 1997.…”

“…This system has been successfully applied to the analysis of many complex samples over the past 14 years since its inception, [72][73][74][75][76][77][78][79][80][81][82][83][84] including trace metals in seawater, [72][73][74]77,83 geological digests, 76,[78][79][80] biological samples, 72,80,82,84 drinking water, 81 fertilizers 79 and reagent grade chemicals. 82 However, here we will briefly focus on the application of chelating stationary phases for the direct analysis of complex sample matrices, so-called high-performance chelation ion chromatography (HPCIC), as last reviewed by Jones and Nesterenko in 1997. 85 To-date the majority of such applications have been carried out using iminodiacetic acid (IDA) modified polymer and silica based substrates, either covalently bonded or dynamically coated onto the surface.…”

Determination of vanadium, molybdenum and tungsten in complex matrix samples by chelation ion chromatography and on-line detection with inductively coupled plasma mass spectrometry

“…For the determination of trace metals in complex sample matrices with chelating resins, termed as chelation ion chromatography (CIC), has received considerable attention in recent years [9][10][11][12][13][14][15][16][17]. The selectivity of a chelating resin is attributed mainly to the nature of the immobilized ligand on the base matrix.…”

“…The exceptionally high selectivity for noble metal ions in acidic solution suggests that the prepared resin could be an ideal stationary phase of CIC for selective preconcentration and separation of soft metal ions from complex sample matrix materials. ␥-Aminobutyrohydroxamate resin had been also evaluated as the stationary phase of CIC for the separation of d-orbital elements and f-orbital elements in complex matrices samples [14,15].…”