γ-Radiation effect on ionic liquid [bmim][BF4]

Effect of gamma irradiation on gas-ionic liquid and water-ionic liquid interfacial stability

“…Although studies by other researchers on the c-radiolysis of ILs containing imidazolium as the cation, but with different anions (PF À 6 , BF À 4 , NTf À 2 ), have shown considerable darkening of the IL with increasing absorbed radiation dose [18][19][20], we have not observed any darkening in the three ILs studied here, even after prolonged radiation exposures (up to 86 h).…”

Corrosion of carbon steel in the [P 14666 ][Br] ionic liquid: The effects of γ-radiation and cover gas

“…Their chemical stability makes them good candidates for use in nuclear applications (such as waste treatment), but for such uses the radiation stability of the ILs and their interactions with materials must be understood. There are a number of reports on the effect of ionizing radiation on nitrogen-based ILs [2][3][4][5][6] but the radiation stability of phosphonium-based ILs is not as well known. We have recently shown that phosphonium-based ILs are generally chemically stable under -irradiation [7].…”

Influence of FeCl3 on radiation stability of ionic liquid BmimCl

“…Allen et al [7] have investigated the radiation stability of 1,3-dialkylimidazolium nitrate/chloride ionic liquids, which are more stable than the mixtures of tributylphosphate and odorless kerosene under similar irradiation conditions. The radiation stability of some imidazolium-based ionic liquids, such as BmimPF 6 , BmimTf 2 N, and BmimBF 4 , has been discussed in our previous study [8,9]. Yuan et al [10][11][12] further confirmed the decomposition species of cation [C 4 mim] + and anions by EMI-MS and titration analysis.…”