Preliminary results are presented from a recent campaign of experiments, performed at the PF1B cold-neutron facility at ILL (Grenoble, France), in which γ-ray spectroscopy of neutron-rich nuclei produced in neutron induced fission on 235 U and 241 Pu targets was performed. By using the EXILL array, consisting of EXOGAM, GASP and ILL-Clover detectors, and a digital triggerless data acquisition system, γ coincidences over several microseconds time windows were studied. This allowed to obtain new information on nuclei around 132 Sn, such as 132 Te, 133 Sb and 130 Sn, in which microsecond isomeric states occur. Preliminary results on 210 Bi, populated by cold-neutron capture, are also shown. The data offer the possibility to investigate the couplings between core excitations and valence particles, around the doubly magic nuclei 132 Sn and 208 Pb.