μ-{4-Methyl-1,2,6-triphosphatricyclo[2.2.1.02,6]heptane-P1,P2,P3}-tris[pentacarbonylchromium(0)]

Anion-templated formation of a unique inorganic ‘super-adamantoid’ cage [Ag6(triphos)4(O3SCF3)4]2+ [triphos = (PPh2CH2)3CMe]

“…This arrangement differs markedly from the 'exomethyl' conformation observed when triphos acts as a face capping ligand. 4 As a consequence, the in-pointing methyls generate an ordered hydrophobic interior and the Ag + and O 3 SCF 3 2 ions form a polar spherical surface.…”