2009
DOI: 10.1107/s160053680901486x
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[μ-N,N,N′,N′-Tetrakis(diphenylphosphinomethyl)benzene-1,4-diamine-κ4P,P′:P′′,P′′′]bis[bis(nitrato-κO)palladium(II)]

Abstract: The asymmetric unit of the title complex, [Pd2(NO3)4(C58H52N2P4)], contains one half-mol­ecule, in which the central benzene ring is located on a crystallographic centre of inversion. The Pd atom has a distorted square-planar coordination consisting of two P and two O atoms. In the crystal structure, inter­molecular C—H⋯O inter­actions link the mol­ecules into chains, and π–π contacts between the phenyl rings [centroid–centroid distance = 3.928 (3) Å] may further stabilize the structure.

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