σ-π-rearrangement of σ-crotylmanganese pentacarbonyl with the retention of the geometric configuration of the allylic ligand

Druz, N.N.; Klepikova, V. I.; Lobach, M. I.; Kormer, V. A.

doi:10.1016/s0022-328x(00)81404-7

Cited by 8 publications

(1 citation statement)

References 2 publications

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“…The 1H-N.M.R. spectra for 1-5, obtained on a Varian FT-80 spectrometer, agreed with that previously reported [42][43][44]. In particular, only the anti-isomer was detected for 1-methyl-~r-allyl-Mn(CO)4.…”

Section: Methodssupporting

confidence: 90%

The low-lying cationic hole-states of η³-allyl tetracarbonyl complexes of Mn and Re

et al. 1983

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1983) The low-lying cationic hole-states of η 3 -allyl tetracarbonyl complexes of Mn and Re, Molecular Physics, 50:1, 113-128,The electronic structure in the ground state and the low-lying cationic hole states in a series of six ,?3-allyl transition metal tetracarbonyl complexes with Mn and Re has been studied by means of molecular orbital calculations and by means of He(I) photoelectron spectroscopy. The computational framework is a semiempirical INDO model. The ionization energies are calculated by means of the Green's function formalism with a second order and a renormalized self-energy approximation. Significant differences in the localization properties of the outer valence orbitals lead to a large deviation in the calculated reorganization energies. Koopmans' theorem is invalid in the manganese series. The interrelation between simple fragment molecular orbital models for transition metal complexes and the nature of the low-lying hole states is analysed.

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Section: Methodssupporting

confidence: 90%

The low-lying cationic hole-states of η³-allyl tetracarbonyl complexes of Mn and Re

et al. 1983

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Metallorganische Lewis‐Säuren, XLVIII. Neue Vorläufer metallorganischer, kationischer Lewis‐Säuren mit zwei freien Koordinationsstellen: (OC)₄Re(OEt₂)FBF₃ und (OC)₂(PPh₃)₂Ru(FBF₃)₂

Krämer¹,

Lippmann²,

Noisternig³

et al. 1993

Chem. Ber.

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One-Carbon, Two-Carbon and Three-Carbon Ligands

Braterman¹

1986

Reactions of Coordinated Ligands

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σ-π-rearrangement of σ-crotylmanganese pentacarbonyl with the retention of the geometric configuration of the allylic ligand

Cited by 8 publications

References 2 publications

The low-lying cationic hole-states of η³-allyl tetracarbonyl complexes of Mn and Re

The low-lying cationic hole-states of η³-allyl tetracarbonyl complexes of Mn and Re

Metallorganische Lewis‐Säuren, XLVIII. Neue Vorläufer metallorganischer, kationischer Lewis‐Säuren mit zwei freien Koordinationsstellen: (OC)₄Re(OEt₂)FBF₃ und (OC)₂(PPh₃)₂Ru(FBF₃)₂

One-Carbon, Two-Carbon and Three-Carbon Ligands

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σ-π-rearrangement of σ-crotylmanganese pentacarbonyl with the retention of the geometric configuration of the allylic ligand

Cited by 8 publications

References 2 publications

The low-lying cationic hole-states of η3-allyl tetracarbonyl complexes of Mn and Re

The low-lying cationic hole-states of η3-allyl tetracarbonyl complexes of Mn and Re

Metallorganische Lewis‐Säuren, XLVIII. Neue Vorläufer metallorganischer, kationischer Lewis‐Säuren mit zwei freien Koordinationsstellen: (OC)4Re(OEt2)FBF3 und (OC)2(PPh3)2Ru(FBF3)2

One-Carbon, Two-Carbon and Three-Carbon Ligands

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The low-lying cationic hole-states of η³-allyl tetracarbonyl complexes of Mn and Re

The low-lying cationic hole-states of η³-allyl tetracarbonyl complexes of Mn and Re

Metallorganische Lewis‐Säuren, XLVIII. Neue Vorläufer metallorganischer, kationischer Lewis‐Säuren mit zwei freien Koordinationsstellen: (OC)₄Re(OEt₂)FBF₃ und (OC)₂(PPh₃)₂Ru(FBF₃)₂