We study the hadronicB 0 s decays based on the existence of the resonant state f J (2220). In particular, we are able to explain the unexpected large experimental result of B(B 0 s → J/ψ pp) = (3.0 +1.2 −1.1 ± 0.52 ± 0.03) × 10 −6 measured recently by the LHCb collaboration due to the resonant contribution inB 0 s → J/ψ f J (2220) with f J (2220) → pp, while it is estimated to be at most of order 10 −9 in terms of the OZI rule without the resonance. In addition, we find that B(B 0 s → D * 0 (f J →) pp) = (4.70 ± 2.89) × 10 −7 , B(B 0 s → J/ψ(f J →)ππ) = (15.6 ± 15.2) × 10 −6 , and B(B 0 s → D * 0 (f J →)ππ) = (24.5 ± 24.4) × 10 −7 , while B(B 0 s → J/ψ(f J →)KK) < 1.6 × 10 −5 and B(B 0 s → D * 0 (f J →)KK) < 2.5×10 −6. Moreover, we predict that the decay branching ratios ofB 0 s → (J/ψ, D * 0) ¯ are (2.68 ± 1.23) × 10 −7 and (2.25 ± 0.80) × 10 −6. Some of the predictedB 0 s decays are accessible to the experiments at the LHCb.