Abstract:The Schiff base ligand H 2 L has been synthesized by condensation of 2-aminophenol with 3-methyl-1phenyl-4-formylpyrazol-5-one and reaction between H 2 L and Ni(OOCR 3 ) 2 , R = H in 1, -CH 3 in 2, Cl in 3, yielded three new tetranuclear Ni(II) complexes. The complexes have been characterized by elemental analysis, IR-and ES-MS spectroscopy. Their structures as well as structure of ligand were determined by single-crystal X-ray diffraction. Compounds 1-3 possesses tetranuclear cubane-like structures containing… Show more
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