Никель-вольфрамовые сульфидные катализаторы, полученные<i>in situ</i>в углеводородной среде<i>,</i>для гидрирования ароматических углеводородов

Сизова, И. А.; Сердюков, С. И.; Максимов, А. Л.

doi:10.7868/s0028242115040115

Нефтехимия

2015

DOI: 10.7868/s0028242115040115

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Никель-вольфрамовые сульфидные катализаторы, полученныеin situв углеводородной среде,для гидрирования ароматических углеводородов

И. А. Сизова¹,

С. И. Сердюков²,

А. Л. Максимов³

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2023

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Effect of Quinoline Additions on the Activity of In Situ Formed NiWS Catalysts

Ziniatullina,

Kuchinskaya,

Knyazeva

et al. 2023

Neftehimiâ

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The effect of quinoline additions and amount of the sulfiding agent added on the activity of the in situ prepared NiWS catalyst in naphthalene hydrogenation was studied. In the presence of 1 wt % quinoline, the obtained catalyst shows high activity (95% naphthalene conversion). The physicochemical properties of the catalyst were studied by XPS, X-ray diffraction analysis, and TEM. At the W : substrate molar ratio of 1 : 40 and 360°С, an increase in the amount of the sulfiding agent from 1 to 5 wt % leads to a decrease in the selectivity with respect to decalins from 68 to 39%, respectively. The degree of decoration with nickel on adding 1 wt % sulfiding agent is 0.1. As the amount of the sulfiding agent added is increased to 5 wt %, the degree of decoration with nickel increases to 0.3.

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Effect of Quinoline Additions on the Activity of In Situ Formed NiWS Catalysts

Ziniatullina,

Kuchinskaya,

Knyazeva

et al. 2023

Neftehimiâ

View full text Add to dashboard Cite

show abstract

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Никель-вольфрамовые сульфидные катализаторы, полученныеin situв углеводородной среде,для гидрирования ароматических углеводородов

Cited by 1 publication

References 0 publications

Effect of Quinoline Additions on the Activity of In Situ Formed NiWS Catalysts

Effect of Quinoline Additions on the Activity of In Situ Formed NiWS Catalysts

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