Электрохимический Контроль Электронной Проводимости Тонких Пленок Металлоорганических Полимеров

Abstract

The dependence of the conductivity in thin films of polymer complexes of nickel with N4 ligands with macrocyclic and chelate structure on the doping level has been studied by the electrochemical in-situ conductance method. The electrochemical conductivity window of polymers depends on the structure of the monomers and approached 1.2 V for the macrocyclic complex. Electrochemical doping changes the electrical resistance of the investigated materials by 4 orders of magnitude