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The optical frequency comb generation schemes mainly include mode-locked laser, electro-optic modulation comb, nonlinear Kerr micro-resonator comb and nonlinear supercontinuum comb. For the nonlinear supercontinuum comb scheme, the silica-based high nonlinear fiber with near-zero flattened normal dispersion is required. However the fiber dispersion has variation along the fiber owing to the fabrication inaccuracy. Furthermore, nonlinear supercontinuum comb generation based on the nonlinear fiber has not been systematically studied. In this paper, an optimal design of four-clad flat normal dispersion high nonlinear silica fiber with a triangular core refractive index distribution for the flat optical frequency comb generation is carried out. The effects of the fiber cladding width and refractive index on the fiber dispersion characteristics and cut-off wavelength were studied through using the finite element method mode solver. The optimally designed fiber can obtain relatively flat near-zero normal dispersion in the wavelength range of 1400~1700 nm, the dispersion range is -3~0<i>ps</i>/(<i>km·nm</i>), and the dispersion slope is close to 0 near 1550 nm. The effective mode field area of the nonlinear silica fiber is about 11<i>μm</i><sup>2</sup>, and the nonlinear coefficient can reach 12.8<i>W</i><sup>-1</sup>·<i>km</i><sup>-1</sup>.Based on the electro-optic modulation pulse pumping the flat normal dispersion high nonlinear silica fiber, the flat optical frequency comb generation is systematically simulated with the generalized nonlinear Schrödinger equation. The time-frequency evolutions of a hyperbolic secant pulse, a Gaussian pulse and a super Gaussian pulse are simulated using the X-Frog technology. The time-frequency spectrograms connect the time and frequency domains of the pulse, which clearly shows the change of pulse chirp during the propagation. The effect of various parameters on the optical frequency comb are studied, such as the fiber length, second-order dispersion, third-order dispersion, pulse peak power, pulse half width, pulse initial chirp, and pulse shape. An optical frequency comb with 3dB flatness and bandwidth of about 40nm can be achieved based on hyperbolic secant pulse or Gaussian pulse pumping. Comparing with the hyperbolic secant pulse and Gaussian pulse, the super Gaussian pulse can produce a flatter optical frequency comb. An optical frequency comb with 2dB flatness and bandwidth of about 92nm can be achieved based on the super Gaussian pulse pumping. Therefore, based on the proposed normal dispersion high nonlinear fiber, it is possible to realize an optical frequency comb with repetition rate above 10GHz, power flatness within 3dB, and spectral bandwidth of about 40~90 nm. The simulation results are beneficial to promote the localization of normal dispersion high nonlinear silica fiber and its application in flat optical frequency comb.
Adding nanofillers to epoxy resin matrices is a common approach to achieve their multi-function, among which boron nitride nanotubes (BNNTs) with one-dimensional nanostructures have attracted much attention because of their ultra-high thermal conductivity, wide energy level band gap, high aspect ratio and mechanical strength. Yet, the strong π-π non-covalent bonding and lip-lip interactions make BNNTs prone to agglomeration in the epoxy resin matrix. Moreover, the different physicochemical properties of BNNTs and epoxy resins as well as the chemical inertness of BNNTs surface lead to the lack of effective interfacial interaction between BNNTs and epoxy resin matrix. Therefore, the performance of the epoxy composite dielectric is not enhanced by simple blending solely, but will even have the opposite effect. To address the problems of BNNTs, in this article, the surface structure of BNNTs was constructed from the perspective of interface modulation by using sol-gel method to coat mesoporous silica (mSiO<sub>2</sub>) on BNNTs surface and further introducing silane coupling agent (KH560). The results indicate that constructing the surface structure of BNNTs can optimize the level of interfacial interaction between BNNTs and epoxy resin matrix, which results in stronger interfacial connection and elimination of internal pore phenomenon. The dielectric constant and loss of the composite dielectric prepared in this way were further reduced, reaching 4.1 and 0.005 respectively at power frequency, which was significantly lower than that of pure epoxy resin. At the same time, the mechanical toughness (3.01 MJ/m<sup>3</sup>) and thermal conductivity (0.34 W/(m·K)) were greatly improved compared with pure epoxy resin. In addition, the unique nano-mesoporous structure of mSiO<sub>2</sub> endowed the composite dielectric with a large number of deep traps, which effectively hinders the migration of electrons, thereby improving the electrical strength of the composite dielectric, and the breakdown field strength reached 95.42 kV/mm. Further, Tanaka multinuclear model was used to systematically investigate the interfacial mechanism of BNNTs surface structure construct on dielectric relaxation and trap distribution of composite dielectrics. The above results indicated that the good interfacial interaction between BNNTs and epoxy resin matrix was crucial for the establishment of the micro-interface structure and the improvement of macroscopic properties of composite dielectrics. This paper offered a novel idea for the multifunctionalities of epoxy resin, and also provided some experimental data support for revealing the correlation between surface properties of nano-fillers, microstructure of composite dielectric and macroscopic properties.
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