The corrosion protection efficiency
of three pyridines namely 2-amino-3,5-dicarbonitrile-4-(4-methoxyphenyl)-6-(phenylthio)pyridine
(ADTP I), 2-amino-3,5-dicarbonitrile-4phenyl-6-(phenylthio) pyridine
(ADTP II), and 2-amino-3,5-dicarbonitrile-4-(4-nitrophenyl)-6-(phenylthio)
pyridine (ADTP III) was investigated by electrochemical impedance
spectroscopy, potentiodynamic polarization, and weight loss techniques.
The results of potentiodynamic polarization studies show that the
three compounds under investigation show mixed-type inhibition behavior.
Among them, ADTP I shows the highest inhibition efficiency of 97.6%
at 1.22 mmol L–1. The effect of temperature and
related activation parameters were worked out. To inspect the surface
morphology and composition of inhibitor film on the mild steel surface,
scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy
(EDX) technique were used.
Hybrid chemosensors, L1 and L2, based on pyridine-2,6-dicarboxamide fragment while containing 4-nitrobenzoxadiazole group have been designed and investigated for the sensing of Al3+ and Fe3+ ions. Detection was found to...
The inhibition effect of three aryl pyrazole pyridine derivatives (APPs) against the corrosion of copper in 0.5 M HCl has been investigated by electrochemical impedance, potentiodynamic polarization measurements and quantum chemical methods.
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