Fluorinated acrylic polymer (FAP) films have been impregnated with silver precursor (Ag(hfac)COD) by supercritical fluid technique and next irradiated with laser (λ = 532 nm). Laser-chemically reduced Ag atoms have been assembled into massifs of Ag nanoparticles (3 -8 nm) in FAP/Ag(hfac)COD films matrix in the form of periodic layered nanostructures (horizontal to film surface) with unexpectedly short period (90 -180 nm). The wavelet analysis of TEM images reveals the existence of even shorter-period structures in such films. Photolysis with non-coherent light or pyrolysis of FAP/Ag(hfac)COD film results in formation of Ag nanoparticles massifs but free of any periodic nanoparticle assemblies. Our interpretation of the observed effect of laser formation of short-period nano-sized Ag nanoparticle assemblies is based on self-enhanced interference process in the course of modification of optical properties of film.

Strong high-quality fiber Bragg gratings with photoinduced refractive-index modulation of more than 10-(3) were written in a Corning SMF-28 fiber, a P(2)O5-doped-core fiber and a pure-silica-core fluorine-doped-cladding fiber by third-harmonic radiation (267 nm, 150 fs and 1.2-1.8x1011 W/cm(2)) of a femtosecond Ti:sapphire laser using a phase mask. We compare the 267-nm photosensitivity responses with the results of irradiation by 193-nm ArF and 157-nm F(2) excimer lasers. The dependence of the refractive-index change on the exposure dose and the annealing characteristics of the fabricated gratings are typical for Type-I UV-written fiber gratings.

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