No abstract

No abstract

No abstract

SUMMARYA thin film of low-viscosity lubricating liquid between a solid wall and a viscous material reduces shear stress on the latter and tends to make it flow as though it were slipping along the wall. The result when the lubricated material is being squeezed out of the gap between approaching parallel plates is flow more nearly irrotational, or extensional, the more effective the lubricating film on the plates. Two Newtonian analyses of this flow situation are reported. One is an approximate, asymptotic analytical solution for Newtonian lubricating flow in the films and combined mixed flow, shear and extension, in the viscous layer. The second is a full twodimensional axisymmetric solution of the momentum and continuity equations along with the kinematic condition which governs the motion of the interface. Both analyses indicate that there are two limiting flow regimes, depending on the ratio of the thickness ofeach of the two phases to radius and on the viscosity ratio of the two liquids. In one limit the flow is parallel squeezing and the lubricant layer slowly thins and persists a long time. In the other the lubricant is expelled preferentially. Implications of the results are discussed for rheological characterization of viscoelastic liquids and for prediction of lubricated or autolubricated flows in processing situations.

Biodegradation of 2,4-dichlorophenoxyacetate (2,4-D) and glucose were studied using a 2,4-D acclimated culture. Biodegradation of glucose by the 2,4-D preacclimated culture follows the typical Monod kinetics after a 20-h lag period in the presence or absence of 2,4-D. Biodegradation of 2,4-D by the same culture follows Andrew's "substrate inhibition" model. When both glucose and 2,4-D are available, mutual inhibition is observed. However, the effect on 2,4-D is masked by the fact that larger concentrations of active biomass are produced when glucose is available. This kind of concurrent utilization and interaction results in a substantial reduction of the mean cell residence time in a continuous flow system. It also extends the area of stability of the process into higher dilution rates as well as into higher influent concentrations.