Systems of three interacting particles are notorious for their complex physical behaviour. A landmark theoretical result in few-body quantum physics is Efimov's prediction of a universal set of bound trimer states appearing for three identical bosons with a resonant two-body interaction. Counterintuitively, these states even exist in the absence of a corresponding two-body bound state. Since the formulation of Efimov's problem in the context of nuclear physics 35 years ago, it has attracted great interest in many areas of physics. However, the observation of Efimov quantum states has remained an elusive goal. Here we report the observation of an Efimov resonance in an ultracold gas of caesium atoms. The resonance occurs in the range of large negative two-body scattering lengths, arising from the coupling of three free atoms to an Efimov trimer. Experimentally, we observe its signature as a giant three-body recombination loss when the strength of the two-body interaction is varied. We also detect a minimum in the recombination loss for positive scattering lengths, indicating destructive interference of decay pathways. Our results confirm central theoretical predictions of Efimov physics and represent a starting point with which to explore the universal properties of resonantly interacting few-body systems. While Feshbach resonances have provided the key to control quantum-mechanical interactions on the two-body level, Efimov resonances connect ultracold matter to the world of few-body quantum phenomena.

We report on the observation of interspecies Feshbach resonances in an ultracold, optically trapped mixture of Rb and Cs atoms. In a magnetic field range up to 300 G we find 23 interspecies Feshbach resonances in the lowest spin channel and 2 resonances in a higher channel of the mixture. The extraordinarily rich Feshbach spectrum suggests the importance of different partial waves in both the open and closed channels of the scattering problem along with higher-order coupling mechanisms. Our results provide, on one hand, fundamental experimental input to characterize the Rb-Cs scattering properties and, on the other hand, identify possible starting points for the association of ultracold heteronuclear RbCs molecules.

We present an analytic model to calculate the atomic scattering length near a Feshbach resonance from data on the molecular binding energy. Our approach considers finite-range square-well potentials and can be applied near broad, narrow, or even overlapping Feshbach resonances. We test our model on Cs2 Feshbach molecules. We measure the binding energy using magnetic-field modulation spectroscopy in a range where one broad and two narrow Feshbach resonances overlap. From the data we accurately determine the Cs atomic scattering length and the positions and widths of two particular resonances.

The observation of a new class of long-lived outer well states of ungerade symmetry (B"B1Sigma+u) in molecular hydrogen, lying above the ionization threshold, is reported. Rovibrational levels within a potential extended over internuclear separations of R = 7-25 a.u. are experimentally investigated in a triple resonance scheme. Good agreement ( <0.5 cm(-1)) with updated ab initio calculations is found for vibrational levels up to v = 26, demonstrating that such calculations can now be extended to this energetic range above ionization, as long as interaction with the Rydberg manifolds is shielded by a barrier. The dynamical behavior (predissociation and autoionization) of this class of " u" symmetry states is remarkably different from similar outer well states of " g" symmetry; this phenomenon can be understood from the structure of doubly excited electronic states.

We present a lifetime measurements of the 6s level of rubidium. We use a time-correlated singlephoton counting technique on two different samples of rubidium atoms. A vapor cell with variable rubidium density and a sample of atoms confined and cooled in a magneto-optical trap. The 5P 1/2 level serves as the resonant intermediate step for the two step excitation to the 6s level. We detect the decay of the 6s level through the cascade fluorescence of the 5P 3/2 level at 780 nm. The two samples have different systematic effects, but we obtain consistent results that averaged give a lifetime of 45.57 ± 0.17 ns.