coverage of more than 180" at teeseismc statons, and standard errors of less than 35 km In location and 15 km in depth. Thls procedure (E. R Engdahl, R. D van der Hilst, R. Buand, in preparaton) ensures that depth errors and the mapping of source heterogenety lnto misocaton are minimzed, thereby creating a poweriul uncontam~nated database of P, pP,
An orthorhombic (space group Pnnm) boron phase was synthesized at pressures above 9 GPa and high temperature, and it was demonstrated to be stable at least up to 30 GPa. The structure, determined by single-crystal x-ray diffraction, consists of B12 icosahedra and B2 dumbbells. The charge density distribution obtained from experimental data and ab initio calculations suggests covalent chemical bonding in this phase. Strong covalent interatomic interactions explain the low compressibility value (bulk modulus is K300=227 GPa) and high hardness of high-pressure boron (Vickers hardness HV=58 GPa), after diamond the second hardest elemental material.
Abstract-Opaque minerals in the Qingzhen (EH3) and MacAlpine Hills (MAC) 88136 (EU) enstatite chondrites were studied and compared with other EH and EL chondrites. All opaque minerals usually occur in multi-sulfide-metal clasts and nodules in the matrix between chondrules . The higher abundance of opaque minerals, the occurrence ofniningerite and various alkalisulfides (e.g., caswellsilverite, phases A and B, djerfisherite) are diagnostic criteria for EH chondrites, while alabandite is characteristic for EL chondrites. In addition, EH chondrites are characterized by enrichments of Si in both kamacite and perryite, and alkali elements in sphalerite and chalcopyrite. The Mn contents of daubreelite and sphalerite are lower in EH than in EL chondrites. These are consistent with lower oxygen fugacity and higher H2S fugacity ofEH than EL chondrites. In contrast, the discovery of sphalerite and Zn-rich daubreelite in MAC 88136 indicates that their absence in EL6 chondrites is probably related to thermal metamorphism in the parent body.Schreibersite micro spherules are commonly enclosed in most sulfides in Qingzhen, but are absent in MAC 88136. They were once molten, and probably predated all sulfide host phases. The petrographic setting and chemical compositions ofthe sulfide hosts ofthe schreibersite micro spherules in EH3 chondrites are consistent with formation by condensation. The earliest sulfide condensates oldhamite and niningerite occupy the interiors of the clasts and nodules, whereas the rims consist of troilite and djerfisherite. In addition, in Qingzhen, some other troilite, djerfisherite and sphalerite assemblages coexist with perryite. They were produced by sulfurization of metallic Fe-Ni in the nebula. In MAC 88136, sulfurization ofSi-bearing Fe-Ni metal is less pronounced, and it produced troilite, schreibersite and less abundant perryite. Two kinds of normal zoning and a reverse zoning trends of niningerite, and both normal and reverse zoning of sphalerite were found in clasts and nodules in Qingzhen. The coexistence ofnormal and reverse zoning profiles in niningerite grains in the same meteorite strongly suggests that they formed before accretion in the parent body, because an asteroidal metamorphic or an impact event in the parent body would have erased these contrasting profiles and destroyed the textural settings. In contrast, alabandite in MAC 88136 shows only normal zoning, with the FeS content decreasing to 9.3 mol% toward troilite, indicating very slow cooling at low temperature.
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