The enthalpy of liquid mercury was measured from 0° to 450° C by the " drop" method .These and other precise published data were used to calculate a number of the rmodynamic properties of liquid and gaseous mercury at the vapor pressures from the triple point , -38.88°, to + 500° C. The entropy calculated from data on the vapor and liq uid was compared with that derived from published low-temperature heat-capacity data for the solid .The calculated values of vapor pressure, also using data on the vapo r and liquid, were fo und to agree over a wide temperature range with certain published experimental values when independently derived gas-imperfection and published temperature-scal e corrections were applied.
Using an improved ice calorimeter and furnace, t he e nthalpy changes of two samples of pure sodium have been accurately meas ured by a drop m ethod at a number of temperatures between 0° and 900° C. Equations are derived to fit t he data, and values of enthalpy and entropy, based on zero values at 0° C, as well as the heat capacity are tabulated for both the solid and liquid. Sources of significant experime ntal error are examined critically, and some theoretical implications of t he results are discussed qualitatively.
Precise mcasurements of the heat capacity of so lid and liquid n-heptane from 20 0 to 523 0 K arc described. An adiabatic calorimeter, with which were determined also the triple point and the heat of fusion, was used from 20 0 to 370 0 I\:, whereas a drop method was used with a Bunsen icc calorimeter from 273 0 to 523 0 K. These two series of heat-capacity measurements and three other se ries of independent values show a maximum difference of approximately 0.25 percent in the range 50 0 to 370 0 K. Besides the heat capacity, tIl(' enthalpy, entropy, and Gibbs free enerp:y of the solid and liquid at saturation pressures from 0 0 to 520 0 K are derived and tabulated. The same properties of the ideal gas from 298 0 to 470 0 K also arc derived by making use of publishcd precise measurements of gaseous heat capacity, heat of vaporization, and the normal boiling point. Interconsistency in the values of t he various thermal properties is shown by the fact that the vapor pressures calculated from these values ap:rce with those precisely measured by other investigators bet\\"een 200 0 and 372 0 K to \\'ithin ± 0.1 percent.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.