Abstract.A commercial low-resolution (0.5 cm −1 ) Fourier Transform Spectrometer (FTS) has been modified and is used for determining the total column XCO 2 of the atmosphere by analysing direct solar radiation. The spectrometer has a small home-built solar tracker attached, so that it is a ready-touse instrument. The results are validated with temporally coinciding on-site measurements taken with a high-resolution Total Carbon Column Observing Network (TCCON) FTIR spectrometer. For the whole comparison period of 5 months (26 measurement days) an agreement with TCCON results of (0.12 ± 0.08) % is achieved. This makes the spectrometer a promising candidate for a low-cost addition to the TCCON core FTIR sites, especially suitable for locations with limited infrastructure. An impressive mechanical and thermal stability is proved, enabling the spectrometer for use in field campaigns and for the monitoring of local sources.
Abstract. The portable FTIR (Fourier transform infrared) spectrometer EM27/SUN, dedicated to the precise and accurate observation of column-averaged abundances of methane and carbon dioxide, has been equipped with a second detector channel, which allows the detection of additional species, especially carbon monoxide. This allows an improved characterisation of observed carbon dioxide enhancements and makes the extended spectrometer especially suitable as a validation tool of ESA's Sentinel 5 Precursor mission, as it now covers the same spectral region as used by the infrared channel of the TROPOMI (TROPOspheric Monitoring Instrument) sensor. The extension presented here does not rely on a dichroic, but instead a fraction of the solar beam is decoupled near the aperture stop of the spectrometer using a small plane mirror. This approach allows maintaining the camera-controlled solar tracker set-up, which is referenced to the field stop in front of the primary detector. Moreover, the upgrade of existing instruments can be performed without alterating the optical set-up of the primary channel and resulting changes of the instrumental characteristics of the original instrument.
A commercial low-resolution (0.5 cm−1) Fourier-Transform-Spectrometer (FTS) has been modified and is used for determining the total column XCO2 of the atmosphere by analyzing direct solar radiation. The spectrometer has a small home-built solar tracker attached, so that it is a ready-to-use instrument. The results are validated with temporally coinciding on-site measurements taken with a high-resolution Total Carbon Column Observing Network (TCCON) FTIR-spectrometer. For the whole comparison period of 5 months (26 measurement days) an agreement with TCCON-results of (0.12 ± 0.08)% is achieved. This makes the spectrometer a promising candidate for a low-cost addition to the TCCON core FTIR sites, especially suitable for locations with limited infrastructure. An impressive mechanical and thermal stability is proved, enabling the spectrometer for use in field campaigns and for the monitoring of local sources
Abstract. Although optical components in Fourier transform infrared (FTIR) spectrometers
are preferably wedged, in practice, infrared spectra typically suffer from the
effects of optical resonances (“channeling”) affecting the retrieval of
weakly absorbing gases. This study investigates the level of channeling of
each FTIR spectrometer within the Network for the Detection of Atmospheric
Composition Change (NDACC). Dedicated spectra were recorded by more than
20 NDACC FTIR spectrometers using a laboratory mid-infrared source and two
detectors. In the indium antimonide (InSb) detector domain (1900–5000 cm−1), we found
that the amplitude of the most pronounced channeling frequency amounts to
0.1 ‰ to 2.0 ‰ of the spectral background level,
with a mean of (0.68±0.48) ‰ and a median of
0.60 ‰. In the mercury cadmium telluride (HgCdTe) detector domain
(700–1300 cm−1), we find even stronger effects, with the largest
amplitude ranging from 0.3 ‰ to 21 ‰ with a mean
of (2.45±4.50) ‰ and a median of 1.2 ‰. For
both detectors, the leading channeling frequencies are 0.9 and 0.11 or
0.23 cm−1 in most spectrometers. The observed spectral frequencies
of 0.11 and 0.23 cm−1 correspond to the optical thickness of the
beam splitter substrate. The 0.9 cm−1 channeling is caused by the
air gap in between the beam splitter and compensator plate. Since the air gap
is a significant source of channeling and the corresponding amplitude differs
strongly between spectrometers, we propose new beam splitters with the wedge
of the air gap increased to at least 0.8∘. We tested the insertion of
spacers in a beam splitter's air gap to demonstrate that increasing the wedge
of the air gap decreases the 0.9 cm−1 channeling amplitude
significantly. A wedge of the air gap of 0.8∘ reduces the
channeling amplitude by about 50 %, while a wedge of about
2∘ removes the 0.9 cm−1 channeling completely. This study
shows the potential for reducing channeling in the FTIR spectrometers operated
by the NDACC, thereby increasing the quality of recorded spectra across the
network.
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