The experimental electron density distribution in glycyl-L-threonine dihydrate has been investigated using single-crystal X-ray diffraction data at 110 K to a resolution of (sin theta/lambda) = 1.2 A(-1). Multipolar pseudo-atom refinement was carried out against 5417 observed data and the molecular electron density was analyzed using topological methods. The experimental electrostatic potential around the molecule is discussed in terms of molecular interactions. Crystal data: C6H12N2O4. 2H2O, Mr = 212.2, orthorhombic, P2(1)2(1)2(1), Z = 4, F(000) = 456 e, T = 110 K, a = 9.572 (3), b = 10.039 (3), c = 10.548 (2) A, V = 1013.6 (4) A3, Dx = 1.3 g cm(-3), mu = 1.2 cm(-1) for lambdaMo = 0.7107 A.
2014 Nous avons étudié la magnétorésistance transverse du (TMTSF)2PF6 pour des champs magnétiques allant jusqu'à 32 T, à basse température jusqu'à 4,2 K. Nous observons des oscillations de Shubnikov-de-Haas directement sur la magnétorésistance pour des champs supérieurs à 18 T, mais il n'est pas du tout certain qu'il existe un champ seuil car la disparition des oscillations peut être expliquée par l'amortissement normal fonction du champ magnétique. Par contre, celles-ci s'évanouissent très rapidement entre 5 et 4,2 K. Ce comportement inhabituel pourrait être dû à une transition de phase. Enfin nous donnons une exploration du champ fondamental en fonction de 03B8 (0 = angle entre B et l'axe c*) qui montre le gondolement des « tubes de Fermi » le long de l'axe c*.Abstract. 2014 The transverse magnetoresistance of (TMTSF)2PF6 has been investigated in magnetic fields up to 32 T, at low temperatures down to 4.2 K. Shubnikov-de-Haas oscillations are directly observed on the magnetoresistance in fields higher than 18 T, but there is no evidence of a threshold field since the disappearance of oscillations can be explained by the normal field-dependent damping. However these oscillations vanish very quickly between 5 and 4.2 K. This unusual behaviour could be related to a phase-transition. Finally an exploration of the fundamental field versus 0 is given (03B8 = angle between B and c*), showing the warping of the « Fermi tubes » along the c* axis. J. Physique Lett. 46 (1985) L-535 -L-542 15 JUIN 1985, Classification Physics Abstracts 72.80L -72.20M -71.25H
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