Excited state aromaticity is a stimulating area of research, widely used as a probe to describe and rationalize many photochemical phenomena. Herein, we review some of the recent findings of unprecedented aromatic stabilization in spin singlet excimer and through-space aromatic character in triplet excimers of a series of linear [n]acenes, as paramount examples of polycyclic aromatic hydrocarbons (PAHs). This review also provides insights on the

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