SummaryWe present a new model for the gas amplification effect used in many environmental scanning electron microscopes, wherein molecular complexity is shown to be the critical factor. Monte Carlo simulations, based on experimental electron scattering cross-sections, are used to deduce a predictive model for the amplification process that is superior to the Townsend gas capacitor model. These predictions are compared with experimentally obtained amplification curves. Significantly, it is shown that the ionization efficiency of the electrons changes dramatically over the gap distance, and a constant value cannot be assumed. Atomic and molecular excitations affect the amplification process in two ways: first, they serve to lower the average kinetic energy of the imaging electrons, thereby keeping a greater fraction near the ionization threshold energy. Second, molecular normal modes determine the effectiveness of positive gas ions in producing additional secondaries upon surface impact. Practical implications such as signal gain and fraction of useful signal as a function of operating conditions are discussed in the light of the new model. Finally, we speculate on potential new contrast mechanisms brought about by the presence of an imaging gas.

In this paper, we present quantitative data on the amplification behaviour of alternative imaging gases in environmental SEM and describe the experimental methods used to obtain them. We investigated the gases' amplification abilities over the pressure range 0 - 12 Torr with respect to the primary beam energy, detector gap distance and detector accelerating field, in order to isolate optimum imaging conditions for each gas. The gases investigated were, in addition to water vapour, nitrous oxide, carbon dioxide, nitrogen and helium.

Hypervelocity micro particles (mass < 1 ng), including meteoroids and space debris, routinely impact spacecraft and produce plasmas that are initially dense ($10 28 m À3), but rapidly expand into the surrounding vacuum. We report the detection of radio frequency (RF) emission associated with electromagnetic pulses (EMPs) from hypervelocity impacts of micro particles in ground-based experiments using micro particles that are 15 orders of magnitude less massive than previously observed. The EMP production is a stochastic process that is influenced by plasma turbulence such that the EMP detection rate that is strongly dependent on impact speed and on the electrical charge conditions at the impact surface. In particular, impacts of the fastest micro particles occurring under spacecraft charging conditions representative of high geomagnetic activity are the most likely to produce RF emission. This new phenomenon may provide a source for unexplained RF measurements on spacecraft charged to high potentials. V

Conventional scanning electron microscopy permits the use of cryogenic techniques, which has led to the examination of ice-containing samples (eg ice cream) at temperatures of -80°C and below. At these temperatures moderate etching of the ice crystals occurs which helps to identify the crystals in the surrounding glassy matrix. However, imaging at higher temperatures - equivalent to those at which most ice-containing systems are actually utilised - is impossible because of rapid sublimation. We have set out to develop a system which will enable us to examine ice crystals at temperatures of -20°C and below, corresponding much more closely to realistic conditions of use.In the environmental scanning electron microscope (ESEM), a gas can be maintained around the sample. Not only can this be used to maintain the sample in its native state, but the gas is actively involved in the imaging process through its role in signal amplification.

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