The ability to process assemblies using thin film techniques in a scalable fashion would be a key to transmuting the assemblies into manufacturable devices. Here, we embed FePt nanoparticle assemblies into a silica thin film by sol-gel processing. Annealing the thin film composite at 650 degrees C transforms the chemically disordered fcc FePt phase into the fct phase, yielding magnetic coercivity values H(c)>630 mT. The positional order of the particles is retained due to the protection offered by the silica host. Such films with assemblies of high-coercivity magnetic particles are attractive for realizing new types of ultra-high-density data storage devices and magneto-composites.

The internal friction of Ca partially substituted Y1−xCaxBa2Cu3O7−δ ceramics was measured using the vibrating reed method from liquid-nitrogen temperature to room temperature at kilohertz frequency. There are two thermally activated relaxation peaks (called P1 and P2 at 95 K and 120 K, respectively). The intensity of P1 almost remains unchanged with Ca substitution, while that of P2 decreases. Another internal friction peak appears around 220 K (called P3). With the increase of Ca content, the intensity of P3 decreases and the peak position shifts toward low temperature. We also have observed that Zn substitution affects P3 much less and Fe substitution seems to result in another contribution to the internal friction around 250 K. We expect that the P3 peak originates from a charge-carrier crossover and possibly has some relationship with the occurrence of the dynamic stripe at low temperature.

The temperature spectra of internal friction for Zn doped ceramic YBa2(Cu1-xZnx)3O6+ are presented with zinc content x varying from 0 to 0.1. Two thermally activated peaks (P1, P2) near the superconducting transition temperature Tc were found to show different behaviours upon zinc doping: the peak at 110 K (P1) decreases rapidly with increasing of x while another one at 120 K (P2) has no significant change. The relaxation mechanism of P1 is interpreted in terms of jumps of apical oxygen atoms between off-centred positions produced by the Jahn-Teller effect. The effect of zinc substitution on the depression of superconductivity is also discussed.

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