In this paper we are interested in studying the copper-indium-gallium-selenium (CIGS) solar cells sandwiched between cadmium sulfide (CdS) and ZnO as buffer layers, and Molybdenum (Mo). Thus, we report our simulation results using the capacitance simulator (SCAPS) in terms of layer thickness, absorber layer band gap and operating temperature to find out the optimum choice. An efficiency of 20.61% (with Voc of 635.2mV, Jsc of 44.08 mA/cm 2 and fill factor of 0.73) has been achieved with CdS used as buffer layer as the reference case. It is also found that the high efficiency CIGS cells with the low temperature were a very high efficiency conversion.
ABSTRACT.It is a matter of controversy why excitons can efficiently dissociate into free carriers at an intrinsic polymer/fullerene interface. While extensive characterization is performed in the course of many reported experimental studies, correlation of performance and physical parameters among studies done in different laboratories is low, pointing out the need to address some aspects of BHJSC active materials that have received relatively some attention. In this paper, we discuss the modeling of MDMO-PPV/PCBM(Poly(2-methoxy-5-(3,7-dimethyloctyloxy)-1,4-phenylenevinylene)/ soluble C60 derivative, methanofullerene, [6,6]-phenyl C61-butyric acid methyl ester organic devices. In our approach, we apply two recent methods so called transfer matrix method and hopping model to calculate the exciton dissociation probability, and photocurrent density versus mixture ratio, electric field and angle of incidence. The results show that EDP (exciton dissociation probability) in solar cells without PEDOT-PSS (Poly (ethylendioxythiophene)-Poly(styrene sulfonic acid)) HTL hole transporting layer is better than the cells with additional layer in enhancing the performance of MDMO-PPV/PCBM solar cells. When the weight ratio of MDMO-PPV is less than 3:5 and 2 :5 respectively, the best exciton dissociation probability, and photocurrent density of solar cell is obtained
It is a matter of controversy why excitons can efficiently dissociate into free carriers at an intrinsic polymer/fullerene interface. While extensive characterization is performed in the course of many reported experimental studies, correlation of performance and physical parameters among studies done in different laboratories is low, pointing out the need to address some aspects of BHJSC active materials that have received relatively some attention. In this paper, we discuss the modeling of MDMO-PPV/PCBM(Poly(2-methoxy-5-(3,7-dimethyloctyloxy)-1,4-phenylenevinylene)/ soluble C60 derivative, methanofullerene, [6,6]-phenyl C61-butyric acid methyl ester organic devices. In our approach, we apply two recent methods so called transfer matrix method and hopping model to calculate the exciton dissociation probability, and photocurrent density versus mixture ratio, electric field and angle of incidence. The results show that EDP (exciton dissociation probability) in solar cells without PEDOT-PSS (Poly (ethylendioxythiophene)-Poly(styrene sulfonic acid)) HTL hole transporting layer is better than the cells with additional layer in enhancing the performance of MDMO-PPV/PCBM solar cells. When the weight ratio of MDMO-PPV is less than 3:5 and 2:5 respectively, the best exciton dissociation probability, and photocurrent density of solar cell is obtained.
This article has as an aim the study and the simulation of the photovoltaic cells containing CdTe materials, contributing to the development of renewable energies, and able to feed from the houses, the shelters as well as photovoltaic stations… etc. CdTe is a semiconductor having a structure of bands with an indirect gap of a value of 1,5 eV at ambient temperature what means that photon wavelength of approximately 1200 nm will be able to generate an electron-hole pair. One speaks about photogeneration. We will lay the stress, initially, on the essential design features of a photovoltaic module (the open-circuit tension, the short-circuit current, the fill factor, and the output of the cell), our results was simulated with the SCAPS computer code in one dimension which uses electrical characteristics DC and AC of the thin layers heterojunctions. The results obtained after optimization are: VCO = 0.632V, Jsc = 39.1 mA/cm2, FF=82.98 % and the output energy of conversion is 18.26%.Optimization is made according to the temperature and the wavelength.
The analysis of the data is currently, in the statisticians, the object of a true phenomenon of mode, characterized at the same time by the passion and the rejection. To determine the characteristics of a whole of data is obviously not an end in itself, but this lapse of memory is unfortunate because the type of data available always influences the direction of research. The factorial analysis in normalized principal components (PCA), is particularly adapted to the reduction of tables of measurements, where one generally works on a matrix of correlation between characters. In this article we will report our results of analysis into 2 and 3 dimensions of the molecular weight and energy of plasmon of semiconductor chalcopyrites by using what one call the datamining materials. All information was presented in the tables envisaged by an ACP method of the semiconductors étudiés. L' analyzes factorial substitutes for primitive measurements of new variables or factors (which are linear combinations of the primitive variables) with the help of which it is thus possible to optimize the visualization of the data in a restricted number of figures.
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