Currently, use of poly(lactic acid) (PLA) for injection molded articles is limited for commercial applications because PLA has a slow crystallization rate when compared with many other thermoplastics as well as standard injection molding cycle times. The overall crystallization rate and final crystallinity of PLA were controlled by the addition of physical nucleating agents as well as optimization of injection molding processing conditions. Talc and ethylene bis-stearamide (EBS) nucleating agents both showed dramatic increases in crystallization rate and final crystalline content as indicated by isothermal and nonisothermal crystallization measurements. Isothermal crystallization halftimes were found to decrease nearly 65-fold by the addition of only 2% talc. Process changes also had a significant effect on the final crystallinity of molded neat PLA, which was shown to increase from 5 to 42%. The combination of nucleating agents and process optimization not only resulted in an increase in final injection molded crystallinity level, but also allowed for a decreased processing time. An increase of over 308C in the heat distortion temperature and improved strength and modulus by upwards of 25% were achieved through these material and process changes.

An investigation was conducted to determine a simple, effective method for reconditioning stainless steel orthodontic attachments in the orthodontic office. In total, 100 new brackets were bonded to premolar teeth, then debonded and the bond strength recorded as a control for the reconditioning process. The debonded brackets were divided into six groups and each group reconditioned using different techniques as follows: attachments in four groups were flamed and then either (1) sandblasted, (2) ultrasonically cleaned, (3) ultrasonically cleaned followed by silane treatment, (4) rebonded without further treatment. Of the two remaining groups, one was sandblasted, while the brackets in the other were roughened with a greenstone. The brackets were rebonded to the premolar teeth after the enamel surfaces had been re-prepared, and their bond strengths measured. The results indicated that sandblasting was the most effective in removing composite without a significant change in bond strength compared with new attachments. Silane application did not improve the bond strength values of flamed and ultrasonically cleaned brackets. Attachments that had only been flamed had the lowest bond strength, followed by those that had been roughened with a greenstone.

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The durability of a commercially available injection molding grade polylactide (PLA) was assessed by exposure to conditions of elevated temperature and humidity over a period of several weeks. Moisture absorption, molecular weight, and mechanical performance were monitored over time and as a function of crystallinity level. At 50 C and 90% relative humidity, both amorphous and crystalline samples of PLA showed significant moisture absorption, allowing hydrolysis to occur. The study showed that while crystalline content had an effect on the initial moisture absorption behavior, the overall longer term effects on degradation were surprisingly minor. A cumulative damage model was used to relate the overall degradation due to moisture uptake and hydrolysis to long-term durability in environments typical of automotive interiors. The study showed that the injection molding grade PLA resins that are currently commercially available are not suitable for use in applications that require long-term durability in environments subject to elevated temperature and humidity.

The high strain-rate constitutive behavior of polymer composites with various natural fibers is studied. Hemp, hemp/glass hybrid, cellulose, and wheat straw-reinforced polymeric composites have been manufactured, and a split-Hopkinson pressure bar apparatus has been designed to measure the dynamic stress-strain response of the materials. Using the apparatus, compressive stress-strain curves have been obtained that reveal the materials' constitutive characteristics at strain rates between 600 and 2400 strain/s. Primary findings indicate that natural fibers in thermoset composites dissipate energy at lower levels of stress and higher strain than glass-reinforced composites. In the case of thermoplastic matrices, the effect on energy dissipation of natural fibers vs. conventional talc reinforcements is highly dependent on resin properties. Natural fibers in polypropylene homopolymer show improved reinforcement but have degraded energy dissipation compared to talc. Whereas in polypropylene copolymer, natural fibers result in improved energy dissipation compared to talc. These data are useful for proper design, analysis, and simulation of lightweight biocomposites.