VLE for (CH 3 Cl + HCl) has been experimentally determined at temperatures (159.01 and 182.33) K, using a static; method. The data were used to calculate the molar excess Gibbs energy at the two temperatures. The excess molar enthalpy estimated from the G E m values for the equimolar mixture is relatively large and negative: H E m ¼ Àð1011 AE 318Þ J AE mol À1 . The results have been compared with estimates from the chemical theory of solutions.
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