Structural model of C 100 H 79 O 7 NS coal organic mass was obtained within density functional theory in the localized orbital basis set using the B3LYP hybrid functional. The model was compared with the known experimental data for coal of different grades and its sorption properties were studied with respect to CH 4 , CO 2 and H 2 O. It has been shown that macromolecule of coal organic mass has bulk structure with a pore inside it. Interaction between coal and CH 4 molecules consists of typical physical adsorption with oligomer formation on the pore border, physical adsorption with elements of chemical adsorption was also observed between coal and H 2 O molecules. Interaction between coal and H 2 O molecules included both physical and chemical adsorbion.
Objective. The article proposes design solutions aimed at the comprehensive modernization of the cold supply system of the ice palace "Puck" in Sochi, to reduce its impact on the environment.Method. A water reuse system has been created and a technology has been developed for using low-temperature heat that is released during the operation of the refrigeration machine.Result. A refrigeration plant has been developed that allows you to utilize, accumulate and direct the heat of condensation for the secondary use of thermal energy by other engineering systems at the facility, thereby reducing heat and greenhouse gas emissions into the Earth's atmosphere and increasing the technological capabilities of cooling.Conclusion. The proposed methods make it possible to make the necessary calculations and select equipment for the implementation of the developed systems in ice arenas.
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