In this work Barium Titanate-Polyvinylpyrrolidone (BaTiO3/PVP) composite nanofibers are synthesized via electrospinning with sol-gel precursor. BaTiO3 nanofibers are obtained after calcinning the composite at 960 °C for 20 h. The morphology and crystal structure of the electrospun composite nanofibers are characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and FT-IR analyses. SEM studies show that the average diameter of the electrospun BaTiO3/PVP composite nanofibers and BaTiO3 nanofibers is 379 nm and 170 nm, respectively. XRD results confirm cubic perovskite crystal structure of BaTiO3 nanofibers and FT-IR spectrum shows the formation of metal oxide bond and other bond in the BaTiO3/PVP composite nanofibers. The SPSS 16 software backward regression has been used to study the effect of the voltage and flow rate on the diameter of BaTiO3/ PVP composite nanofibers and to obtain the standard equation governing the production of composite nanofibers. 978-1-4799-5622-7/$31.00 ©2014 IEEE