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In this work an experimental and simulation study of batch and semicontinuous styrene/butadiene emulsion copolymerization process was developed. The mathematical model combines the classical emulsion copolymerization equations, with mass balances, partitioning of components among all liquid phases, micellar and homogenous nucleation mechanisms and mass transfer equations between liquid and gaseous phases. Simulation results show good agreement with experimental measurements of conversion, average particle diameter and pressure.

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This paper introduces a complex representation for spacelike surfaces in the Lorentz-Minkowski space L 4 , based in two complex valued functions which can be assumed to be holomorphic or anti-holomorphic. When the immersion is contained in quadrics of L 4 , the representation then allows us to obtain interesting partial differential equations with holomorphic or anti-holomorphic parameters, within which we find the partial Riccati Equation. Using then theory of holomorphic complex functions we construct explicitly new local solutions for those PDEs together with its associated geometric solutions. So, several explicit examples are given. As geometric consequence, through of our approach we characterize all conformal totally umbilical spacelike immersions into L 4 , and in addition, we also show that for each conformal immersion in L 4 which satisfies the partial Riccati equation there exists a Bryant immersion in H 3 , both immersions being congruent by a translation vector.