Less than two years after the discovery of high temperature superconductivity in oxypnictide LaFeAs(O,F) several families of superconductors based on Fe layers (1111, 122,11, 111) are available. They share several characteristics with cuprate superconductors that compromise easy applications, such as the layered structure, the small coherence length, and unconventional pairing, On the other hand the Fe-based superconductors have metallic parent compounds, and their electronic anisotropy is generally smaller and does not strongly depend on the level of doping, the supposed order parameter symmetry is s wave, thus in principle not so detrimental to current transmission across grain boundaries. From the application point of view, the main efforts are still devoted to investigate the superconducting properties, to distinguish intrinsic from extrinsic behaviours and to compare the different families in order to identify which one is the fittest for the quest for better and more practical superconductors. The 1111 family shows the highest T c , huge but also the most anisotropic upper critical field and in-field, fan-shaped resistive transitions reminiscent of those of cuprates, while the 122 family is much less anisotropic with sharper resistive transitions as in low temperature superconductors, but with about half the T c of the 1111 compounds. An overview of the main superconducting properties relevant to applications will be presented. Upper critical field, electronic anisotropy parameter, intragranular and intergranular critical current density will be discussed and compared, where possible, across the Fe-based superconductor families. 2 , to the ab-plane. 12 The temperature dependence is very different in the two directions, strongly departing from the WHH behaviour 16 mainly in the direction parallel to c. The anisotropy evaluated as γ = ab c ab c H H H ⊥ = 2 // 2 / γ, is also strongly temperature dependent, reminiscent of the two-gap behaviour seen in MgB 2 . 17,18 However, a different situation is observed in the 122 family. (Ba,K)Fe 2 As 2 single crystals exhibit nearly isotropic μ 0 H c2 with

High purity epitaxial FeSe0.5Te0.5 thin films with different thickness were grown by Pulsed Laser Ablation on different substrates. By varying the film thickness, Tc up to 21K were observed, significantly larger than the bulk value. Structural analyses indicated that the a axis changes significantly with the film thickness and is linearly related to the Tc. The latter result indicates the important role of the compressive strain in enhancing Tc. Tc is also related to both the Fe-(Se,Te) bond length and angle, suggesting the possibility of further enhancement.Tc=21K in epitaxial FeSe0.5Te0.5 thin films with biaxial compressive strain Ver. 04/12/2009 14:29:00 2 Since the discovery of the iron based superconductors 1 , great efforts have been devoted to the preparation of thin films of the various phases 2 -7 and references therein. Between other reasons, the interest in films deposition is motivated by the strong Tc dependence on external and chemical pressure in iron based pnictides and calcogenides 8 -12 , which has suggested the idea of exploring whether a similar effect can be induced by strain in thin films. Indeed, such expectation turned out to be true: in Ba(Fe1-xCox)2As2 thin films 7 deposited on various substrates, Tc has been observed to increase with the ratio c/a. Also in FeSe0.5Te0.5 thin films an increase of Tc has been obtained by two groups 5,6 in particular a maximum Tc of 17K has been measured. Such increase has been attributed to the observed c axis decrease with respect to the bulk value.Here we present preparation as well as structural, morphological and physical characterization of epitaxial FeSe0.5Te0.5 thin films with different thickness, deposited on different substrates. A maximum Tc =21K was obtained, which is a remarkable 30% increase with respect to the bulk value.The films were grown by Pulsed Laser Ablation Deposition (PLD) in ultra high vacuum system 13 starting from a FeSe0.5Te0.5 (Fe(Se,Te)) target prepared by direct synthesis from high purity materials (Fe 99.9+%, Se 99.9% and Te 99.999%) 5 .With the aim of introducing biaxial strain we deposited films on single crystal substrates with different cell parameters, namely magnesium oxide (MgO a=4.217 Å) , strontium titanate (STO a=3.905 Å ), lantanum aluminate (LAO a=3.789 Å), and yttria stabilized zirconia (ZrO:Y, a=3.637 Å); for all the substrates we used the (001) orientation. The deposition conditions were optimized as reported in a previous paper 5 ; namely, we used a deposition temperature of 550°C at a pressure of 5·10 -Tc=21K in epitaxial FeSe0.5Te0.5 thin films with biaxial compressive strain Ver. 04/12/2009 14:29:00 3 9 mBar. The laser repetition rate was 3 Hz (248 nm wavelength) and the laser fluency was 2 J/cm 2 (2 mm 2 spot size). The target-substrate distance was maintained at 5 cm.In order to study the residual strain behaviour, films of different thickness from 1.2 nm to 600 nm were deposited; the thickness was calibrated by X-ray reflectometry.XRD analysis allowed to identify the PbO-like tetragon...

The nuclear and magnetic structure of Fe 1+y (Te 1-x ,Se x ) (0 ≤ x ≤ 0.20) compounds was analyzed between 2 K and 300 K by means of Rietveld refinement of neutron powder diffraction data.Samples with x ≤ 0.075 undergo a tetragonal to monoclinic phase transition at low temperature, whose critical temperature decreases with increasing Se content; this structural transition is strictly coupled to a long range antiferromagnetic ordering at the Fe site. Both the transition to a monoclinic phase and the long range antiferromagnetism are suppressed for 0.10 ≤ x ≤ 0.20. The onset of the structural and of the magnetic transition remains coincident with the increase of Se substitution. The low temperature monoclinic crystal structure has been revised. Superconductivity arises for x ≥ * Corresponding author: amartin@chimica.unige.it 0.05, therefore a significant region where superconductivity and long range antiferromagnetism coexist is present in the pseudo-binary FeTe -FeSe phase diagram.