Plasma technology applied to textiles is a dry, environmentally‐ and worker‐friendly method to achieve surface alteration without modifying the bulk properties of different materials. In particular, atmospheric non‐thermal plasmas are suited because most textile materials are heat sensitive polymers and applicable in a continuous processes. In the last years plasma technology has become a very active, high growth research field, assuming a great importance among all available material surface modifications in textile industry. The main objective of this review is to provide a critical update on the current state of art relating plasma technologies applied to textile industry.
This work studies the surface characteristics, antimicrobial activity, and aging effect of plasma-pretreated polyamide 6,6 (PA66) fabrics coated with silver nanoparticles (AgNPs), aiming to identify the optimum size of nanosilver exhibiting antibacterial properties suitable for the manufacture of hospital textiles. The release of bactericidal Ag(+) ions from a 10, 20, 40, 60, and 100 nm AgNPs-coated PA66 surface was a function of the particles' size, number, and aging. Plasma pretreatment promoted both ionic and covalent interactions between AgNPs and the formed oxygen species on the fibers, favoring the deposition of smaller-diameter AgNPs that consequently showed better immediate and durable antimicrobial effects against Gram-negative Escherichia coli and Gram-positive Staphylococcus aureus bacteria. Surprisingly, after 30 days of aging, a comparable bacterial growth inhibition was achieved for all of the fibers treated with AgNPs <100 nm in size. The Ag(+) in the coatings also favored the electrostatic stabilization of the plasma-induced functional groups on the PA66 surface, thereby retarding the aging process. At the same time, the size-related ratio (Ag(+)/Ag(0)) of the AgNPs between 40 and 60 nm allowed for the controlled release of Ag(+) rather than bulk silver. Overall, the results suggest that instead of reducing the size of the AgNPs, which is associated with higher toxicity, similar long-term effects can be achieved with larger NPs (40-60 nm), even in lower concentrations. Because the antimicrobial efficiency of AgNPs larger than 30 nm is mainly ruled by the release of Ag(+) over time and not by the size and number of the AgNPs, this parameter is crucial for the development of efficient antimicrobial coatings on plasma-treated surfaces and contributes to the safety and durability of clothing used in clinical settings.
Improvement of existing properties and the creation of new material properties are the most important reasons for the functionalization of textiles. Polymer nanocomposites offer the possibility of developing a new class of nanofinishing materials for textiles with their own manifold of structure property relationship only indirectly related to their components and their micron and macro-scale composite counterparts. Though polymer nanocomposites with inorganic filler of different dimensionality and chemistry are possible, efforts have only begun to uncover the wealth of possibilities of these new materials. Approaches to modify the polymer nanocomposite system by various inorganic or organic substances can lead to a huge number of additional functionalities which are increasingly demanded by the textile industries. In this review, we have compiled the current research in polymer nanocomposite-based nanofinishes for multifunctional textiles which provides a snapshot of the current experimental and theoretical tools being used to advance our understanding of polymer nanocomposites and their applications in textiles.
It is known that the dynamic equations of motion for constrained mechanical multibody systems are frequently formulated using the Newton-Euler's approach, which is augmented with the acceleration constraint equations. This formulation results in the establishment of a mixed set of partial differential and algebraic equations, which are solved in order to predict the dynamic behavior of general multibody systems. The classical resolution of the equations of motion is highly prone to constraints violation because the position and velocity constraint equations are not fulfilled. In this work, a general and comprehensive methodology to eliminate the constraints violation at the position and velocity levels is offered. The basic idea of the described approach is to add corrective terms to the position and velocity vectors with the intent to satisfy the corresponding kinematic constraint equations. These corrective terms are evaluated as function of the Moore-Penrose generalized inverse of the Jacobian matrix and of the kinematic constraint equations. The described methodology is embedded in the standard method to solve the equations of motion based on the technique of Lagrange multipliers. Finally, the effectiveness of the described methodology is demonstrated through the dynamic modeling and simulation of different planar and spatial multibody systems. The outcomes in terms of constraints violation at the position and velocity levels, conservation of the total energy and computational efficiency are analyzed and compared with those obtained with the standard Lagrange multipliers method, the Baumgarte stabilization method, the augmented Lagrangian formulation, the index-1 augmented Lagrangian and the coordinate partitioning method.
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