In this article, results of PET track-etched membranes (PET TeMs) hydrophobized by photo-induced graft polymerization of stearyl methacrylate (SM) inside the pores were presented. The effects of monomer concentration, time of irradiation and the nature of the solvent on the degree of grafting and membrane morphology were investigated. The PET TeMs with pore diameters ranging from 350 nm (pore density of 1 × 108 pore/cm2) to 3.05 µm (pore density of 1 × 106 pore/cm2) were hydrophobized and tested for oil–water separation by using hexadecane–water and chloroform–water emulsions. Studies have shown high separation performance for membranes (up to 1100 mL/m2·s) with large pore diameters while achieving a high degree of purification.
The present paper addresses the problem of identification of microstructural, nanomechanical, and tribological properties of thin films of tantalum (Ta) and its compounds deposited on stainless steel substrates by direct current magnetron sputtering. The compositions of the obtained nanostructured films were determined by energy dispersive spectroscopy. Surface morphology was investigated using atomic force microscopy (AFM). The coatings were found to be homogeneous and have low roughness values (<10 nm). The values of microhardness and elastic modulus were obtained by means of nanoindentation. Elastic modulus values for all the coatings remained unchanged with different atomic percentage of tantalum in the films. The values of microhardness of the tantalum films were increased after incorporation of the oxygen and nitrogen atoms into the crystal lattice of the coatings. The coefficient of friction, CoF, was determined by the AFM method in the “sliding” and “plowing” modes. Deposition of the coatings on the substrates led to a decrease of CoF for the coating-substrate system compared to the substrates; thus, the final product utilizing such a coating will presumably have a longer service life. The tantalum nitride films were characterized by the smallest values of CoF and specific volumetric wear.
The adhesion of platelets to the surface of implants and stents depends on the material’s properties, such as surface roughness, topography and wettability. The present study analyzes the composition and surface properties of nanostructured Ta, Ta2O5 and TaON coatings and their correlation with the adhesion of platelets. The surface morphology and topography were observed by atomic force microscopy and electron scanning microscopy; while the elemental distribution and chemical composition were analyzed by energy dispersive X-ray spectroscopy. The coated surfaces’ advancing contact angles were evaluated by tensiometric measurements. The surface free energy (SFE) was calculated by the Owens, Wendt, Rabel and Kaeble method. The results of in vitro tests demonstrated that the deposition of Ta-based coatings leads to a decrease in the platelets adhesion and agglomeration ability.
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