In this manuscript, we consider the matrix Sylvester Volterra integro-dynamic system on time scales YΔ(t) = A(t)Y (t) + Y (t)B(t) + μ(t)A(t)Y (t)B(t) + ∫tt0(L1(t, s)Y (s) + Y (s)L2(t, s))Δs + C(t)U(t). In this system convert to an equivalent system of Kronecker product Volterra integro- dynamic system on time scales with the help of a vectorization operator. we establish a sufficient condition for the controllability, observability, and stability aspects of the matrix Sylvester Volterra integro-dynamic system on time scales. Moreover, generalize to a time scales some known properties relating to stability from the case of continuous analysis.2010 Mathematics Subject Classification. Primary:34A37. Secondary:34N05, 34D05, 45D05.