Water scarcity and strict legislation make water reuse in dye related industries like textile and leather become more important. Among the different types of dyes, soluble dyes are the most problematic. Nanofiltration was vital for the treatment of dye wastewater but the major limitation is fouling. Coagulation/flocculation can be effective to enhance nanofiltration performance towards water reuse and minimisation of fouling. The selection of the coagulant type (metal or polymer) and dosages are very critical in this technique. Factors that improved the coagulation were studied in detail and suitable metal coagulants were presented. Cationic, anionic and natural polymers as flocculant aids were also reported for successfully enhancing dye removal. Adding a suitable type of metal coagulant-polymer at an optimum dosage and mixing conditions increases the dye removal at a wider range of operating pH and reduces the production of sludge. In-depth studies on the effect of metal coagulant-polymer on membrane fouling are still lacking and visualisation techniques might be helpful in this regard.
High consumption of process water and water scarcity has motivated industry to reuse their wastewater. Membrane processes are vital to produce water for reuse from dyeing baths in the tanning industry. In this regard, synthetic dye was recognised as the major foulant. To minimise the membrane fouling, coagulation/flocculation process is an
The removal of C.I. Acid Black 210 dye from highly concentrated solutions was studied using a coagulation/flocculation process. Aluminium sulphate was used as a primary coagulant and five commercial polymers were used as flocculant aids. The five commercial polymers were ACCEPTA 2058 (poly-diallyl-dimethyl ammonium chloride), ACCEPTA 2047 (high molecular mass (MM) anionic polyacrylamide), ACCEPTA 2111 (high MM cationic polyacrylamide), ACCEPTA 2105 (Low-medium MM cationic polyacrylamide) and ACCEPTA 2037 (Composite of high MM cationic polyacrylamide-inorganic salt(s)). The five polymers behaved differently and they showed maximum colour removal increment in the order: ACCEPTA 2058 > ACCEPTA 2037 > ACCEPTA 2111 approximately = ACCEPTA 2047 > ACCEPTA 2105. Results also showed that the aluminium sulphate is important as primary coagulant and settling time has significant effect on the dye removal.
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